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The shortest wavelength in hydrogen spec...

The shortest wavelength in hydrogen spectrum of Lyman series
when `R_(H)=109678 cm^(-1)` is :-

A

`1002.7overset(@)A`

B

`1215.67overset(@)A`

C

`1127.30overset(@)A`

D

`911.7overset(@)A`

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AI Generated Solution

The correct Answer is:
To find the shortest wavelength in the hydrogen spectrum of the Lyman series, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Formula**: The formula for the wavelength in the hydrogen spectrum is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant for hydrogen, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. 2. **Determine \( n_1 \) and \( n_2 \)**: For the Lyman series, the transition starts from \( n_2 \) to \( n_1 \): - The lowest energy level \( n_1 \) for the Lyman series is 1. - The maximum energy level \( n_2 \) approaches infinity (as we want the shortest wavelength). 3. **Substitute Values**: Substitute \( n_1 = 1 \) and \( n_2 = \infty \) into the formula: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{1^2} - \frac{1}{\infty^2} \right) \] Since \( \frac{1}{\infty^2} = 0 \), the equation simplifies to: \[ \frac{1}{\lambda} = R_H \left( 1 - 0 \right) = R_H \] 4. **Insert the Value of \( R_H \)**: Given \( R_H = 109678 \, \text{cm}^{-1} \): \[ \frac{1}{\lambda} = 109678 \] 5. **Calculate \( \lambda \)**: To find \( \lambda \), take the reciprocal: \[ \lambda = \frac{1}{109678} \, \text{cm} \] Calculating this gives: \[ \lambda \approx 9.1170 \times 10^{-6} \, \text{cm} \] 6. **Convert to Angstroms**: Since 1 Angstrom = \( 10^{-8} \, \text{cm} \), we convert: \[ \lambda = 9.1170 \times 10^{-6} \, \text{cm} \times \frac{10^{10} \, \text{Å}}{1 \, \text{cm}} = 911.7 \, \text{Å} \] 7. **Final Answer**: The shortest wavelength in the hydrogen spectrum of the Lyman series is: \[ \lambda \approx 911.7 \, \text{Å} \]
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