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Assertion:- The reaction quotient Q, has...

Assertion:- The reaction quotient Q, has the same presentation form as the equilibrium constant K and Q is evaluated using any given concentrations of the species involved in the reaction, and not necesssarily equilibrium concenetrations.
Reason:- If the numerical value of Q is not the same as the value of equilibrium constant, that time reaction will never proceed.

A

If both Assertion `&` Reason are True `&` the Reason is a correct explanation of the Assertion.

B

If both Assertion `&` Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion `&` Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion-reason question, we need to analyze both the assertion and the reason separately. ### Step 1: Analyze the Assertion The assertion states: "The reaction quotient Q has the same presentation form as the equilibrium constant K, and Q is evaluated using any given concentrations of the species involved in the reaction, and not necessarily equilibrium concentrations." - **Explanation**: - The reaction quotient \( Q \) is calculated using the concentrations of reactants and products at any point in time, not just at equilibrium. - The expression for \( Q \) is similar to that of the equilibrium constant \( K \), which is defined at equilibrium. - For a general reaction \( aA + bB \rightleftharpoons cC + dD \), the expressions are: - \( K = \frac{[C]^c [D]^d}{[A]^a [B]^b} \) (at equilibrium) - \( Q = \frac{[C]^c [D]^d}{[A]^a [B]^b} \) (at any time) Thus, the assertion is **true**. ### Step 2: Analyze the Reason The reason states: "If the numerical value of Q is not the same as the value of the equilibrium constant, that time reaction will never proceed." - **Explanation**: - This statement is **false**. - If \( Q \) is not equal to \( K \), it does not mean the reaction will not proceed. Instead: - If \( Q < K \), the reaction will shift to the right (towards products) to reach equilibrium. - If \( Q > K \), the reaction will shift to the left (towards reactants) to reach equilibrium. - Therefore, the reaction can proceed in either direction depending on the relationship between \( Q \) and \( K \). Thus, the reason is **false**. ### Conclusion - The assertion is true, and the reason is false. Therefore, the correct answer is that the assertion is true, but the reason is false. ### Final Answer Assertion: True Reason: False Correct Option: C ---
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