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Assertion:- Fructose does not contain an...

Assertion:- Fructose does not contain an aldehyde group but still reduce tollen's reagent.
Reason:- In presence of dilute solution of alkali, fructose undergoes epimerisation to form glucose and mannose.

A

If both Assertion `&` Reason are True `&` the Reason is a correct explanation of the Assertion.

B

If both Assertion `&` Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion `&` Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion-reason question, we will analyze both the assertion and the reason step by step. ### Step 1: Analyze the Assertion **Assertion:** Fructose does not contain an aldehyde group but still reduces Tollens' reagent. - **Explanation:** - Fructose is a ketone (specifically a ketose) and does not have an aldehyde group. However, it can still reduce Tollens' reagent because it is classified as an alpha-hydroxy ketone. - The presence of the hydroxyl group (-OH) on the carbon adjacent to the carbonyl group (C=O) allows fructose to undergo tautomerization to form an aldehyde in situ, which is capable of reducing Tollens' reagent. ### Step 2: Analyze the Reason **Reason:** In the presence of a dilute solution of alkali, fructose undergoes epimerization to form glucose and mannose. - **Explanation:** - Epimerization is a type of isomerization that involves the conversion of one epimer to another by changing the configuration at one specific carbon atom. - In the case of fructose, when treated with a dilute alkali, it can rearrange to form glucose and mannose, which are epimers of each other at the second carbon atom. ### Step 3: Conclusion - Both the assertion and the reason are true. - The reason correctly explains the assertion because the ability of fructose to reduce Tollens' reagent can be attributed to its conversion to glucose and mannose in the presence of alkali. ### Final Answer Both the assertion and reason are true, and the reason is the correct explanation of the assertion. ---
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