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Assertion:- Ter-butyl chloride on treatm...

Assertion:- Ter-butyl chloride on treatment with Na metal gives isobutane and Isobutylene.
Reason:- It is known as wurtz reaction.

A

If both Assertion `&` Reason are True `&` the Reason is a correct explanation of the Assertion.

B

If both Assertion `&` Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion `&` Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about ter-butyl chloride and its reaction with sodium metal, we will break it down step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that ter-butyl chloride (tert-butyl chloride) on treatment with sodium metal gives isobutane and isobutylene. - Tert-butyl chloride has the structure: \[ (CH_3)_3CCl \] 2. **Reaction with Sodium Metal**: - When tert-butyl chloride reacts with sodium metal, it does not undergo the Wurtz reaction, which typically involves the coupling of two alkyl halides to form alkanes. - Instead, it undergoes an elimination reaction due to the presence of a tertiary carbon, leading to the formation of alkenes and alkanes. 3. **Products of the Reaction**: - The products formed from the reaction of tert-butyl chloride with sodium metal are: - Isobutane (C4H10), which is a saturated hydrocarbon. - Isobutylene (C4H8), which is an unsaturated hydrocarbon (alkene). - The reaction can be summarized as: \[ (CH_3)_3CCl + 2Na \rightarrow C_4H_{10} + C_4H_8 + 2NaCl \] 4. **Conclusion on Assertion**: - The assertion is **true** because tert-butyl chloride does yield isobutane and isobutylene upon reaction with sodium metal. 5. **Understanding the Reason**: - The reason states that this reaction is known as the Wurtz reaction. - The Wurtz reaction typically involves the coupling of two alkyl halides (usually primary) in the presence of sodium to form alkanes, not alkenes. 6. **Conclusion on Reason**: - The reason is **false** because the reaction of tert-butyl chloride with sodium does not fit the definition of the Wurtz reaction, as it produces alkenes rather than alkanes. 7. **Final Answer**: - Since the assertion is true and the reason is false, the correct answer is: **Assertion is true, but the reason is false**.
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