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The strongest base among the following i...

The strongest base among the following is:-

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest base among the given options, we will analyze the ability of each base to donate electrons based on their hybridization and resonance structures. ### Step-by-Step Solution: 1. **Identify the Options**: We need to analyze the structures of the bases provided in the options. Let's denote them as Option 1, Option 2, Option 3, and Option 4. 2. **Analyze Option 1**: - The structure has a nitrogen atom that is sp² hybridized. - In sp² hybridization, the lone pair of electrons is involved in resonance and is not easily available for donation. - Due to this resonance and the acidic character of sp² hybridized nitrogen, it holds the lone pair more effectively. - **Conclusion**: This option is not the strongest base. **Hint**: Remember that sp² hybridized atoms tend to hold onto their lone pairs more tightly due to their involvement in resonance. 3. **Analyze Option 2**: - This structure also has a nitrogen atom with its lone pair in conjugation with a ring. - The lone pair participates in resonance, which reduces its availability for donation. - **Conclusion**: This option is also not the strongest base. **Hint**: Look for resonance structures; they can stabilize lone pairs and reduce basicity. 4. **Analyze Option 3**: - The nitrogen in this structure is sp³ hybridized. - In sp³ hybridization, the lone pair is not involved in resonance and is more available for donation. - Therefore, this nitrogen can easily donate its lone pair, making it a stronger base compared to the previous options. - **Conclusion**: This option is likely the strongest base so far. **Hint**: Sp³ hybridized atoms generally have more available lone pairs for donation, increasing basicity. 5. **Analyze Option 4**: - This structure is aniline, where the nitrogen lone pair is again in resonance with the aromatic ring. - The resonance delocalizes the lone pair, making it less available for donation. - **Conclusion**: This option is not the strongest base. **Hint**: Again, check for resonance; it can significantly affect the availability of lone pairs. 6. **Final Comparison**: - After analyzing all options, we find that Option 3, with the sp³ hybridized nitrogen, has the highest basicity. - Options 1, 2, and 4 are less basic due to resonance effects and hybridization. ### Final Answer: The strongest base among the given options is **Option 3**.
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