Home
Class 12
CHEMISTRY
Assertion:- Halogen acid react with alco...

Assertion:- Halogen acid react with alcohol to form haloalkanes.
Reason:- Order of reactivity of halogen acid
`HClgtHBrgtHI`

A

If both Assertion `&` Reason are True `&` the Reason is a correct explanation of the Assertion.

B

If both Assertion `&` Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion `&` Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question, we need to analyze both statements carefully. ### Step 1: Analyze the Assertion The assertion states that halogen acids react with alcohols to form haloalkanes. - **Reaction Overview**: The general reaction can be represented as: \[ \text{ROH} + \text{HX} \rightarrow \text{RX} + \text{H}_2\text{O} \] Here, ROH is the alcohol, HX is the halogen acid (like HCl, HBr, HI), RX is the haloalkane formed, and H2O is water. - **Conclusion**: The assertion is **true** because halogen acids do indeed react with alcohols to form haloalkanes. ### Step 2: Analyze the Reason The reason states the order of reactivity of halogen acids as HCl > HBr > HI. - **Reactivity Order**: The correct order of reactivity for halogen acids is actually HI > HBr > HCl. This is because the bond strength of the H-X bond decreases as we move from HCl to HI, making HI the most reactive. - **Conclusion**: The reason is **false** because the order given is incorrect. ### Final Conclusion - Since the assertion is true and the reason is false, the correct answer is: **Assertion is true, but reason is false.**
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

Order of stability of halogen oxides :-

The order of reactivity of halogens with methane is

The order of reactivity of halogens towards hydrogen is

Bond strength of halogen acids are

Order of reactivity of halogen acids towards an alcohol is: (HCl,HBr,HI)

The decreasing order of electron affinity of halogen's is

In general the order of reactivity of halogens with transition metals is

Reducing properties of halogen acid are

Account for the following: (i) In reaction involving cleavage of carbon-oxygen bond of alcohols some acid is added to facilitate the reaction. (ii) The order of reactivity of halogen acids with alcohols is HI gt HBr gt HCl . (iii) Phenols do not undergo substitution at the carbon of C-OH bond.

Correct order of boiling point of halogens is