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The value of effective atomic number of ...

The value of effective atomic number of Ni in `[Ni(CO_(4))]` is

A

35

B

27

C

33

D

36

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The correct Answer is:
C
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Ni^(+2) form a complex inon in water having the formula [Ni(H_(2)O)_(6)]^(+2) . How many of the following statement are true for the complex ion ? (i) The complex is octahedral in shape (ii) The complex is diamagnetic in nature . (iii) Ni^(+2) has incompletely filled 3d subshell. (iv). Secodary valency of Ni^(+2) is 6 (v) All the bonds (metal-ligand ) are perpendicular to each other. (vi) All the 3d orbitals of Ni^(+2) are degenerate (vii) Total spin of the complex is 1. (viii) The hybridisation of Ni^(+2) is d^(2)sp^(3) (ix) The complex is more stable than [Ni(en)_(3)]^(+2) (x) Effective atomic number of Ni^(+2) is 36.

Calculate the effective atomic number of the metal atoms in the following complexes / complex ions. (A) [Cr(CO)_(6)]" "(b)[Fe(CN)_(6)]^(3-) " " (c )[Co(CN)_(6)]^(4-)" " [Ni(NH_(3))_(6)]^(2+) [Cr=24,Fe=26,Co=27 and Ni=28 as atomic numbers]

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