Home
Class 12
CHEMISTRY
Which one is the oxidising agent in the ...

Which one is the oxidising agent in the reaction given below
`2CrO_(4)^(2-)+2H^(+)rarrCr_(2)O_(7)^(-2)+H_(2)O`

A

`H^(+)`

B

`Cr_(2)O_(7)^(-2)`

C

`Cr^(++)`

D

None

Text Solution

AI Generated Solution

The correct Answer is:
To determine the oxidizing agent in the reaction: \[ 2 \text{CrO}_4^{2-} + 2 \text{H}^+ \rightarrow \text{Cr}_2\text{O}_7^{2-} + \text{H}_2\text{O} \] we need to analyze the oxidation states of the elements involved in the reaction. ### Step 1: Identify the oxidation states 1. **Chromate ion (\(\text{CrO}_4^{2-}\))**: - The oxidation state of oxygen is \(-2\). - Let the oxidation state of chromium be \(x\). - The equation for the chromate ion is: \[ x + 4(-2) = -2 \implies x - 8 = -2 \implies x = +6 \] - Therefore, the oxidation state of chromium in \(\text{CrO}_4^{2-}\) is \(+6\). 2. **Dichromate ion (\(\text{Cr}_2\text{O}_7^{2-}\))**: - The oxidation state of oxygen is still \(-2\). - Let the oxidation state of chromium be \(y\). - The equation for the dichromate ion is: \[ 2y + 7(-2) = -2 \implies 2y - 14 = -2 \implies 2y = 12 \implies y = +6 \] - Therefore, the oxidation state of chromium in \(\text{Cr}_2\text{O}_7^{2-}\) is also \(+6\). 3. **Hydrogen ions (\(\text{H}^+\))**: - The oxidation state of hydrogen is \(+1\). 4. **Water (\(\text{H}_2\text{O}\))**: - The oxidation state of hydrogen is \(+1\) and oxygen is \(-2\). ### Step 2: Analyze the changes in oxidation states - In this reaction, the oxidation state of chromium does not change: - From \(\text{CrO}_4^{2-}\) (Cr is +6) to \(\text{Cr}_2\text{O}_7^{2-}\) (Cr is still +6). - The oxidation state of hydrogen also does not change: - From \(\text{H}^+\) (H is +1) to \(\text{H}_2\text{O}\) (H is still +1). ### Step 3: Conclusion Since there is no change in the oxidation states of chromium or hydrogen, there is no oxidation or reduction occurring in this reaction. Therefore, there is no oxidizing agent present. ### Final Answer The correct option is **none**. ---
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 3|30 Videos
  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 4|27 Videos
  • REDOX REACTIONS

    ALLEN|Exercise Exercise - 1|61 Videos
  • Redox Reaction

    ALLEN|Exercise All Questions|19 Videos
  • s-Block element

    ALLEN|Exercise All Questions|14 Videos

Similar Questions

Explore conceptually related problems

Which of the following statement is not true for the reaction given below: [Cu(H_(2)O)_(4)]^(2+)+ 4NH_(4) hArr [Cu(NH_(3))_(4)]^(2+)+4H_(2)O

Which of the following statement is not true for the reaction given below: [Cu(H_(2)O)_(4)]^(2+)+ 4NH_(4) hArr [Cu(NH_(3))_(4)]^(2+)+4H_(2)O

The ion acting as an oxidising agent in the reaction, Cr_(2)O_(7)^(2-)+6Fe^(2+)+14H^(+)to2Cr^(3+)+6Fe^(3+)+7H_(2)O is

The equivalent mass of oxidising agent in the following reaction is SO_(2)+2H_(2)Srarr3S+2H_(2)O

What is the reaction given below, called ? H_(2)O_((l)) + H_(2)O_((l)) hArr H_(3)O_((aq))^(+) + OH_((aq))^(-)

Identify the substance undergoing oxidation, the substance undergoing reduction, the oxidising agent and the reducing agent in each of the following reactions. Cr_(2)O_(7)^(2-)+6Fe^(2+)+14H^(+)to2Cr^(3+)+6Fe^(3+)+7H_(2)O

Three different solutions of oxidising agents KMnO_(4),K_(2)Cr_(2)O_(7) " and "I_(2) is titrated separately with 0.158 gm of Na_(2)S_(2)O_(3) . If molarity of each oxidising agent is 0.1 M and reactions are : I. MnO_(4)^(-)+S_(2)O_(3)^(2-) toMnO_(2)+SO_(4)^(2-) II CrO_(7)^(2-)+S_(2)O_(3)^(2-) to Cr^(3+)+SO_(4)^(2-) III. I_(2)+S_(2)O_(3)^(2-) to S_(4)O_(6)^(2-)+I^(-)

Na_(2)CrO_(4)+HCl to H_(2)Cr_(2)O_(7)+Na_(2)SO_(4)

Na_(2)CrO_(4)+HCl to H_(2)Cr_(2)O_(7)+Na_(2)SO_(4)

H_(2)O_(2) acts as an oxidising agent in

ALLEN-REDOX REACTIONS-EXERICSE - 2
  1. Phosphorus has the oxidation state of +3 in

    Text Solution

    |

  2. Which of the following reactions involves oxidation-reduction ?

    Text Solution

    |

  3. Which one is the oxidising agent in the reaction given below 2CrO(4)...

    Text Solution

    |

  4. The oxidation number of arsenic atom in H(3)AsO(4) is :-

    Text Solution

    |

  5. In substance Mg(HXO(3)), the oxidation number of X is :-

    Text Solution

    |

  6. In the following change 3Fe+4H2OrarrFe3O4 +4H2 If the atomic weight of...

    Text Solution

    |

  7. In the course of a chemical reaction an oxidant -

    Text Solution

    |

  8. Which statement is wrong?

    Text Solution

    |

  9. Identify the correct statement with respect to the following reaction,...

    Text Solution

    |

  10. Which of the following reactions involves neither oxidation nor reduct...

    Text Solution

    |

  11. In the reaction :- C+4HNO(3)rarrCO(2)+2H(2)O+4NO(2) HNO(3) acts as...

    Text Solution

    |

  12. In the following reaction the value of 'X' is H(2)O+SO(3)^(2-)rarr S...

    Text Solution

    |

  13. The oxidation number of P in KH(2)PO(3) is ..........

    Text Solution

    |

  14. The oxidation number of iron in potassium ferricyanide [K(3)Fe(CN)(6)]...

    Text Solution

    |

  15. The oxidation number of phosphorus in PH(4)^(+),PO(2)^(3-),PO(4)^(3-) ...

    Text Solution

    |

  16. Which of the following compounds are arranged in increasing oxidation ...

    Text Solution

    |

  17. Iodine shows the highest oxidation state in the compound :-

    Text Solution

    |

  18. The number of electrons required to balance the following equation are...

    Text Solution

    |

  19. Cr(2)O(7)^(-2)+I^(-)+H^(+)rarrCr^(+3)+I(2)+H(2)O The equivalent weig...

    Text Solution

    |

  20. The sum of the oxidation states of all the carbon atoms present in the...

    Text Solution

    |