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Thallium(Tl) Show +1 stable oxidation st...

Thallium(Tl) Show +1 stable oxidation state due to because

A

Of high reactivity

B

Of inert pair effect

C

Of its amphoteric nature

D

It is a transition metal

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The correct Answer is:
To understand why thallium (Tl) shows a +1 stable oxidation state, we can break down the explanation into a series of steps: ### Step-by-Step Solution: 1. **Identify the Element**: - Thallium (Tl) is a chemical element with the atomic number 81. 2. **Determine the Electron Configuration**: - The electron configuration of thallium can be written as: \[ [Xe] 4f^{14} 5d^{10} 6s^{2} 6p^{1} \] - This shows that thallium has a filled inner shell (xenon core) and additional electrons in the outermost shell. 3. **Understand the Oxidation States**: - Thallium can exhibit multiple oxidation states, primarily +1 and +3. - The +1 oxidation state is achieved by losing one 6p electron, while the +3 oxidation state is achieved by losing both 6s and 6p electrons. 4. **Inert Pair Effect**: - The +1 oxidation state is more stable due to the inert pair effect. - The inert pair effect refers to the tendency of the outermost s-electrons (in this case, the 6s electrons) to remain non-bonding or "inert" in heavier elements of the p-block. 5. **Stability of +1 Oxidation State**: - In heavier p-block elements like thallium, the +1 oxidation state becomes more stable because the 6s electrons are less likely to participate in bonding due to their higher energy and the inert pair effect. - Thus, Tl prefers to exhibit the +1 oxidation state over the +3 state. 6. **Conclusion**: - Therefore, thallium shows a +1 stable oxidation state primarily due to the inert pair effect, which stabilizes the +1 state over the +3 state. ### Final Answer: Thallium (Tl) shows a +1 stable oxidation state due to the inert pair effect, which makes the +1 state more stable compared to the +3 state. ---
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