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Na(2)S(2)O(3) is oxidized by I(2) to giv...

`Na_(2)S_(2)O_(3)` is oxidized by `I_(2)` to give

A

`Na_(2)S`

B

`NaHSO_(3)`

C

`NaSO_(4)`

D

`Na_(2)S_(4)O_(6)`

Text Solution

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The correct Answer is:
To solve the problem of what `Na₂S₂O₃` (sodium thiosulfate) produces when oxidized by `I₂` (iodine), we can follow these steps: ### Step 1: Write the Reactants We start with the reactants given in the problem: - Sodium thiosulfate: `Na₂S₂O₃` - Iodine: `I₂` ### Step 2: Write the Reaction When sodium thiosulfate reacts with iodine, it undergoes oxidation. The balanced chemical reaction can be written as: \[ \text{Na}_2\text{S}_2\text{O}_3 + \text{I}_2 \rightarrow \text{Na}_2\text{S}_4\text{O}_6 + \text{NaI} \] ### Step 3: Balance the Reaction To ensure the reaction is balanced, we can check the number of atoms on both sides: - On the left: 2 Na, 2 S, 3 O, and 2 I - On the right: 2 Na (from Na₂S₄O₆ and NaI), 4 S (from Na₂S₄O₆), 6 O (from Na₂S₄O₆), and 1 I (from NaI) After balancing, we find: \[ 2 \text{Na}_2\text{S}_2\text{O}_3 + \text{I}_2 \rightarrow \text{Na}_2\text{S}_4\text{O}_6 + 2 \text{NaI} \] ### Step 4: Determine Oxidation States Next, we determine the oxidation states of sulfur in both compounds: 1. In `Na₂S₂O₃`: - Let the oxidation state of S be \( x \). - The equation is: \( 2x + 2(-2) + 3(-2) = 0 \) - Solving gives \( x = +2 \). 2. In `Na₂S₄O₆`: - Let the oxidation state of S be \( y \). - The equation is: \( 4y + 6(-2) = 0 \) - Solving gives \( y = +2.5 \). ### Step 5: Conclusion From the reaction and the oxidation states, we conclude that sodium thiosulfate (`Na₂S₂O₃`) is oxidized by iodine (`I₂`) to produce sodium tetrathionate (`Na₂S₄O₆`) and sodium iodide (`NaI`). ### Final Answer Thus, the final product of the oxidation of `Na₂S₂O₃` by `I₂` is: \[ \text{Na}_2\text{S}_4\text{O}_6 \] ---

To solve the problem of what `Na₂S₂O₃` (sodium thiosulfate) produces when oxidized by `I₂` (iodine), we can follow these steps: ### Step 1: Write the Reactants We start with the reactants given in the problem: - Sodium thiosulfate: `Na₂S₂O₃` - Iodine: `I₂` ### Step 2: Write the Reaction ...
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