Home
Class 12
CHEMISTRY
With the help of hybridisation show that...

With the help of hybridisation show that aryl halides are lesser reactive than alkyl halides.

Text Solution

Verified by Experts


In alkyl halide (methyl chloride) halogen is attached to sp-hybridised carbon atom. But in aryl halides (chlorobenzene) halogen atom is attached to sp2 hybridized carbon-atom: Now as the size of `sp^2` hybridized orbital is smaller than sp3 hybridized orbital of carbon. So C-Cl bond in aryl halide is smaller than C-Cl bond in alkyl halides. As a result C-Cl bond in aryl halide is stronger than in alkyl halides.
Promotional Banner

Topper's Solved these Questions

  • HALOALKANES AND HALOARENES

    OMEGA PUBLICATION|Exercise MULTIPLE CHOICE QUESTIONS (MCQS)|20 Videos
  • H.P BOARD MARCH,2016

    OMEGA PUBLICATION|Exercise SERIES-C|25 Videos
  • POLYMERS

    OMEGA PUBLICATION|Exercise QUESTIONS |98 Videos

Similar Questions

Explore conceptually related problems

With the help of resonance show that aryl halides are lesser reactive than alkyl halides.

With the help of polarity of the carbon halogen bond show that aryl halides are less reactive than alkyl halides.

In general, alkyl halides are more reactive than aryl halides.

Why aryl halide(haloarenes) are less reactive than alkyl halide(haloalkanes)?

Give reasons : Alkyl halides are better solvents than aryl halides.

How are amines prepared from alkyl halide?

What are aryl halides? Give one example?

OMEGA PUBLICATION-HALOALKANES AND HALOARENES-MULTIPLE CHOICE QUESTIONS (MCQS)
  1. With the help of hybridisation show that aryl halides are lesser react...

    Text Solution

    |

  2. Ethyl alcohol gives ethyl chloride with the help of

    Text Solution

    |

  3. CH3 -CH =CH2 +HI to X where X is

    Text Solution

    |

  4. The reaction CH3 -CH =CH2 +HBr to CH3 - underset(Br) underse...

    Text Solution

    |

  5. SN^1 reaction of alkylhalides leads to

    Text Solution

    |

  6. Most reactive metal is:

    Text Solution

    |

  7. The reactivity order of halides for dehydrohalogenation is

    Text Solution

    |

  8. Mg reacts with RBr best in

    Text Solution

    |

  9. Both methane and ethane can be prepared in single step by the use of

    Text Solution

    |

  10. Alkyl halides react with Mg in dry ether to form

    Text Solution

    |

  11. Which of the following metal can be used for carrying out Wurtz-Fittig...

    Text Solution

    |

  12. Ethyl alcohol gives ethyl chloride with the help of

    Text Solution

    |

  13. CH3 -CH =CH2 +HI to X where X is

    Text Solution

    |

  14. The reaction CH3 -CH =CH2 +HBr to CH3 - underset(Br) underse...

    Text Solution

    |

  15. SN^1 reaction of alkylhalides leads to

    Text Solution

    |

  16. Most reactive halide towards SNI reaction is

    Text Solution

    |

  17. The reactivity order of halides for dehydrohalogenation is

    Text Solution

    |

  18. Mg reacts with RBr best in

    Text Solution

    |

  19. Both methane and ethane can be prepared in single step by the use of

    Text Solution

    |

  20. Alkyl halides react with Mg in dry ether to form

    Text Solution

    |

  21. Which of the following metal can be used for carrying out Wurtz-Fittig...

    Text Solution

    |