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Which one of the following is more basic...

Which one of the following is more basic?

A

Aniline

B

p-Methoxyaniline

C

p-Nitroaniline

D

Benzyl amine

Text Solution

Verified by Experts

The correct Answer is:
D
In aniline, p-methoxyaniline and p-nitroaniline, the lone pair of electrons on the N- atom are delocalized into the benzene ring while in benzylamine they are not, so benzyl amine is most basic .
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ACCURATE PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN COMPOUNDS-MULTIPLE CHOICE QUESTIONS
  1. Which is formed when (CH3)4 NOH is heated ?

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  2. The one which is least basic is

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  3. Which one of the following is more basic?

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  4. Which of the following-statement is not correct?

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  5. The correct order of increasing basicity in aqueous solution is

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  6. The amine that does not react with acetyl chloride is

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  7. Aniline on reaction with acetyl chloride gives

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  8. CH3 CH2CI + NaCN to X+Ni//H2 to Y+ Acetic anhydride to Z. Z in...

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  9. Consider the following reaction C6H5NO2+Sn//HCl to X+C6H5COCl ...

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  10. Hinsberg reagent is

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  11. Write the reactions of aliphatic primary amines with nitrous acid.

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  12. Diazonium salts are reaction products between nitrous acid and

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  13. Aniline reacts with NaNO2 and HCl at room temperature to give

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  14. Which of the following reacts with NaNO2 + HCl at 273-278 K to give al...

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  15. In the diazotisation of aryl amines with sodium nitrite and hydrochlor...

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  16. Name any three food items each rich in protein, dietary fibre?

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  17. Phenyl isocyanide is prepared by which of the following reaction?

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  18. Unpleasant smelling carbylamines are formed by heating alkali and chlo...

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  19. Which of the following compounds cannot be identified by carbylamine t...

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  20. Whenbenzenediazonium chloride in hydrochloric acid reacts with cuprous...

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