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The number of molecules in one litre of ...

The number of molecules in one litre of an ideal gas at 300 K and 2 atmospheric pressure with mean kinetic energy `2xx10^(-9)` J per molecules is :

A

`0.75 xx 10^(11)`

B

`3xx10^(11)`

C

`1.5 xx 10^(11)`

D

`6xx10^(11)`

Text Solution

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The correct Answer is:
To solve the problem of finding the number of molecules in one liter of an ideal gas at 300 K and 2 atmospheric pressure with a mean kinetic energy of \(2 \times 10^{-9}\) J per molecule, we can follow these steps: ### Step 1: Understand the Mean Kinetic Energy Formula The mean kinetic energy (\(K\)) of a molecule in an ideal gas is given by the formula: \[ K = \frac{3}{2} k_B T \] where: - \(k_B\) is the Boltzmann constant (\(1.38 \times 10^{-23} \, \text{J/K}\)), - \(T\) is the temperature in Kelvin. ### Step 2: Relate Mean Kinetic Energy to Temperature Given that the mean kinetic energy per molecule is \(2 \times 10^{-9}\) J, we can rearrange the formula to find \(T\): \[ T = \frac{2K}{3k_B} \] Substituting the values: \[ T = \frac{2 \times (2 \times 10^{-9})}{3 \times (1.38 \times 10^{-23})} \] ### Step 3: Calculate the Temperature Calculating \(T\): \[ T = \frac{4 \times 10^{-9}}{4.14 \times 10^{-23}} \approx 9.66 \times 10^{13} \, \text{K} \] However, we already know the temperature is given as 300 K, so we can proceed with the next step. ### Step 4: Use the Ideal Gas Law The ideal gas law is given by: \[ PV = nRT \] Where: - \(P\) is the pressure in Pascals, - \(V\) is the volume in cubic meters, - \(n\) is the number of moles, - \(R\) is the universal gas constant (\(8.314 \, \text{J/(mol K)}\)), - \(T\) is the temperature in Kelvin. ### Step 5: Convert Units Convert the pressure from atmospheres to Pascals: \[ P = 2 \, \text{atm} = 2 \times 1.013 \times 10^5 \, \text{Pa} = 2.026 \times 10^5 \, \text{Pa} \] Convert the volume from liters to cubic meters: \[ V = 1 \, \text{L} = 1 \times 10^{-3} \, \text{m}^3 \] ### Step 6: Calculate the Number of Moles Rearranging the ideal gas law to solve for \(n\): \[ n = \frac{PV}{RT} \] Substituting the values: \[ n = \frac{(2.026 \times 10^5) \times (1 \times 10^{-3})}{(8.314) \times (300)} \] ### Step 7: Calculate \(n\) Calculating \(n\): \[ n = \frac{2.026 \times 10^2}{2494.2} \approx 0.0812 \, \text{mol} \] ### Step 8: Calculate the Number of Molecules To find the number of molecules (\(N\)), we use Avogadro's number (\(N_A = 6.022 \times 10^{23} \, \text{molecules/mol}\)): \[ N = n \times N_A = 0.0812 \times 6.022 \times 10^{23} \approx 4.89 \times 10^{22} \, \text{molecules} \] ### Final Answer Thus, the number of molecules in one liter of the ideal gas at the given conditions is approximately: \[ N \approx 4.89 \times 10^{22} \, \text{molecules} \]
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