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For a reaction of order n, the unit of t...

For a reaction of order n, the unit of the constant is :

A

`mol^(1-n) L^(1-n)s`

B

`mol^(1-n)L^(2n)s^(-1)`

C

`mol^(-1) L^(n-1)s^(-1)`

D

`mol^(1-n) L^(1-n)s^(-1)`

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The correct Answer is:
To determine the unit of the rate constant (k) for a reaction of order n, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Rate of Reaction**: The rate of a reaction can be expressed as: \[ \text{Rate} = k [A]^n \] where \( k \) is the rate constant, \( [A] \) is the concentration of the reactant, and \( n \) is the order of the reaction. 2. **Define the Units of Rate**: The rate of reaction is generally expressed in terms of concentration change per unit time. The units for rate are: \[ \text{Rate} = \frac{\text{moles}}{\text{liter} \cdot \text{second}} = \text{mol L}^{-1} \text{s}^{-1} \] 3. **Express Concentration in Terms of Units**: The concentration \( [A] \) is measured in moles per liter (mol/L). Therefore, the units of concentration are: \[ [A] = \text{mol L}^{-1} \] 4. **Substitute Units into the Rate Equation**: Rearranging the rate equation for \( k \): \[ k = \frac{\text{Rate}}{[A]^n} \] Substituting the units: \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{(\text{mol L}^{-1})^n} \] 5. **Simplify the Units**: The denominator becomes: \[ (\text{mol L}^{-1})^n = \text{mol}^n \text{L}^{-n} \] Therefore, substituting back into the equation for \( k \): \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol}^n \text{L}^{-n}} = \text{mol}^{1-n} \text{L}^{n-1} \text{s}^{-1} \] 6. **Final Expression for Units of Rate Constant**: Thus, the unit of the rate constant \( k \) for a reaction of order \( n \) is: \[ k = \text{mol}^{1-n} \text{L}^{n-1} \text{s}^{-1} \] ### Conclusion: The unit of the rate constant for a reaction of order \( n \) is: \[ \text{mol}^{1-n} \text{L}^{n-1} \text{s}^{-1} \]
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