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Staggered and eclipsed conformers of eth...

Staggered and eclipsed conformers of ethane are :

A

Polymers

B

Rotamers

C

Enantiomers

D

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To determine the staggered and eclipsed conformers of ethane, we need to understand the molecular structure and the concept of conformers. ### Step-by-Step Solution: 1. **Understanding Ethane Structure**: Ethane (C2H6) consists of two carbon atoms (C) bonded to each other, with three hydrogen atoms (H) attached to each carbon. The molecular formula is CH3-CH3. 2. **Defining Conformers**: Conformers are different spatial arrangements of the same molecule that can be interconverted by rotation around single bonds. In ethane, the rotation around the C-C bond leads to different conformers. 3. **Eclipsed Conformer**: - In the eclipsed conformer, the hydrogen atoms on the front carbon are aligned directly with the hydrogen atoms on the back carbon. - This arrangement leads to torsional strain due to the repulsion between the electron clouds of the overlapping hydrogen atoms. - The dihedral angle (θ) between the hydrogen atoms in the eclipsed form is 0 degrees. 4. **Staggered Conformer**: - In the staggered conformer, the hydrogen atoms on the front carbon are positioned between the hydrogen atoms on the back carbon, minimizing steric hindrance. - This arrangement is more stable than the eclipsed form because it reduces torsional strain. - The dihedral angle (θ) between the hydrogen atoms in the staggered form is 60 degrees. 5. **Conclusion**: - The staggered conformer is more stable due to less steric hindrance and torsional strain. - The eclipsed conformer is less stable due to increased steric hindrance and torsional strain. ### Final Answer: - The staggered conformer has a dihedral angle of 60 degrees, while the eclipsed conformer has a dihedral angle of 0 degrees.
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JEE MAINS PREVIOUS YEAR-JEE MAINS 2021-CHEMISTRY (SECTION-A)
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