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CO(2) gas adsorbs on charcoal following ...

`CO_(2)` gas adsorbs on charcoal following Freundlich adsorption isotherm. For a given amount of charcoal, the mass of `CO_(2)` adsorbed becomes 64 times when the pressure of `CO_(2)` is doubled.
The value of n in the Freundlich isotherm equation is ________ ` xx 10^(-2)`. (Round off to the Nearest Integer)

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To solve the problem, we will use the Freundlich adsorption isotherm equation, which is given by: \[ \frac{x}{m} = k p^{\frac{1}{n}} \] where: - \( x \) is the mass of the gas adsorbed, - \( m \) is the mass of the adsorbent (charcoal), - \( k \) is a constant, - \( p \) is the pressure of the gas, - \( n \) is a constant that indicates the adsorption intensity. ### Step 1: Set up the initial conditions Let: - \( x_1 \) be the mass of \( CO_2 \) adsorbed at pressure \( p_1 \). - \( x_2 \) be the mass of \( CO_2 \) adsorbed at pressure \( p_2 \). According to the problem, when the pressure is doubled, the mass of \( CO_2 \) adsorbed becomes 64 times the initial amount: \[ x_2 = 64 x_1 \] ### Step 2: Express the pressures Since the pressure is doubled, we have: \[ p_2 = 2 p_1 \] ### Step 3: Write the Freundlich isotherm equations for both states Using the Freundlich isotherm for both conditions, we have: 1. For \( p_1 \): \[ \frac{x_1}{m} = k p_1^{\frac{1}{n}} \] 2. For \( p_2 \): \[ \frac{x_2}{m} = k (2 p_1)^{\frac{1}{n}} \] ### Step 4: Substitute \( x_2 \) in terms of \( x_1 \) Substituting \( x_2 = 64 x_1 \) into the second equation gives: \[ \frac{64 x_1}{m} = k (2 p_1)^{\frac{1}{n}} \] ### Step 5: Divide the two equations Dividing the second equation by the first equation: \[ \frac{64 x_1/m}{x_1/m} = \frac{k (2 p_1)^{\frac{1}{n}}}{k p_1^{\frac{1}{n}}} \] This simplifies to: \[ 64 = \frac{(2 p_1)^{\frac{1}{n}}}{p_1^{\frac{1}{n}}} \] ### Step 6: Simplify the right side This can be simplified as follows: \[ 64 = 2^{\frac{1}{n}} \] ### Step 7: Solve for \( n \) Taking logarithms on both sides: \[ \log(64) = \frac{1}{n} \log(2) \] Since \( 64 = 2^6 \), we have: \[ 6 \log(2) = \frac{1}{n} \log(2) \] Dividing both sides by \( \log(2) \): \[ 6 = \frac{1}{n} \] Thus, we find: \[ n = \frac{1}{6} \] ### Step 8: Convert \( n \) to the required format To express \( n \) in the form of \( xx \times 10^{-2} \): \[ n = \frac{1}{6} = 0.1666... \approx 0.17 \times 10^{-2} \] ### Step 9: Round off to the nearest integer The nearest integer to \( 0.17 \times 10^{-2} \) is \( 17 \). ### Final Answer The value of \( n \) in the Freundlich isotherm equation is: \[ \boxed{17} \]
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