Home
Class 12
CHEMISTRY
R - CN overset((i) DIBAL - H ) underset(...

`R - CN overset((i) DIBAL - H ) underset((ii)H _(2) O )to R - Y`
Consider the above reaction and identify `Y`

A

`-CH_(2) NH _(2)`

B

`-CONH_(2)`

C

`-CHO`

D

`-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction step by step, starting from the alkyl cyanide (R-CN) and determining what Y is after the reaction with DIBAL-H followed by hydrolysis. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is an alkyl cyanide, represented as R-CN. The cyanide group (CN) consists of a carbon triple-bonded to a nitrogen atom. 2. **Reaction with DIBAL-H**: DIBAL-H (Diisobutylaluminium hydride) is a reducing agent that can reduce nitriles (CN) to imines. During this reaction, the CN group will be reduced to form an intermediate imine (R-CH=NH-Al(i-Bu)2). - The nitrogen in the CN group donates its lone pair to bond with aluminum, forming a complex. - The carbon atom in the cyanide group becomes electron-deficient and forms a double bond with nitrogen while breaking the triple bond. 3. **Formation of Imine**: The reaction results in the formation of an imine (R-CH=NH) where the nitrogen is now bonded to aluminum and has a positive charge due to the electron donation. 4. **Hydrolysis of the Imine**: The next step involves hydrolysis, where water (H2O) is added. The imine undergoes hydrolysis to form an aldehyde. - The double bond between carbon and nitrogen breaks, allowing the carbon to bond with an oxygen atom from water. - This results in the formation of an aldehyde (R-CHO), where the nitrogen is replaced by an oxygen atom. 5. **Identify Y**: After the hydrolysis, the product formed is R-CHO. Hence, Y in the reaction is the aldehyde group (CHO). ### Final Answer: Thus, Y is identified as CHO.
Promotional Banner

Topper's Solved these Questions

  • JEE MAINS 2021

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY (SECTION-B)|40 Videos
  • JEE MAINS 2021

    JEE MAINS PREVIOUS YEAR|Exercise Chemistry Section A |40 Videos
  • JEE MAINS 2021

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY|30 Videos
  • JEE MAINS 2020

    JEE MAINS PREVIOUS YEAR|Exercise CHEMSITRY|25 Videos
  • JEE MAINS 2022

    JEE MAINS PREVIOUS YEAR|Exercise CHEMISTRY (SECTION-B)|10 Videos

Similar Questions

Explore conceptually related problems

R-C-=N overset(1.DIBAL)underset(2. H_2O)to

CH_(3)CH_(2)-overset(O)overset(||)C-O-C_(2)H_(2)overset((i)DIBAL.H(1 eq))underset((ii)H_(3)O^(+)) to A+B A and B are respectively.

In the reaction, H_3C-CH=CH-CH_2-CH_2-CN overset((i)AIH(t-Bu)_2 )underset((ii) H_2O)rarr Identify the product formed in the given reaction.

Ethyl benzene overset((i) KmNO_(4)//OH^(-))underset((ii) H^(+)//H_(2)O)toX Predicted X in above reaction

Propene overset(HBr)rarr A overset((i)"Mg/ether")underset((ii)H_(2)O //"Boil")rarr B In the above sequence of reactions B is

underset((alpha))(C_(3)H_(5)N) overset("Hydrolysis")(to) underset((x)) (CH_(3)H_(6)O_(2)) underset((ii)H_(3)O^(+)) overset((i) Cl_(2)//P_("red"))to underset((y))(C_(3)H_(5)O_(2)Cl) overset (NH_(3))(to) underset((z)) (C_(3)H_(7)O_(2)) correct option (s) is/are for the above reaction.

R-C-= N overset(SnCl_2 +HCI ) to X overset(H_3 O^+ ) to Y. this reaction is :

JEE MAINS PREVIOUS YEAR-JEE MAINS 2021-CHEMISTRY (SECTION-A)
  1. Which one of the following set of elements can be detected using sodiu...

    Text Solution

    |

  2. Consider the above reaction, the major product "P" formed is :-

    Text Solution

    |

  3. The number of neturons and electrons, respectively, present in the rad...

    Text Solution

    |

  4. Match List -I with List II:

    Text Solution

    |

  5. Given below are two statement : one is labelled as Assertion A and t...

    Text Solution

    |

  6. The CORRECT order of first ionisation enthalpy is :

    Text Solution

    |

  7. Given below are two statements : Statement I : Hyperconjugation is a...

    Text Solution

    |

  8. Given below are two statements : Statement I: [Mn ( CN ) (6) ] ^(3-)...

    Text Solution

    |

  9. To an aqueous solution containing ions such as Al ^(3+), Zn ^(2+) , ...

    Text Solution

    |

  10. Given below are two statements : Statement I : Pencillin is a bact...

    Text Solution

    |

  11. Compound A gives D-Galactose and D-Glucose on hydrolysis. The compound...

    Text Solution

    |

  12. R - CN overset((i) DIBAL - H ) underset((ii)H (2) O )to R - Y Consid...

    Text Solution

    |

  13. consider the above reaction, and choose the correct statement :

    Text Solution

    |

  14. Match List -I with List -II: Choose the correct answer from the o...

    Text Solution

    |

  15. If the Thompson model of the atom was correct, then the result of Ruth...

    Text Solution

    |

  16. Number of Cl = O bonds in chlorous acid, chloric acid and perchloric a...

    Text Solution

    |

  17. Select the correct statements. (A) Crystalline solids have long ran...

    Text Solution

    |

  18. What is A in the following reaction ?

    Text Solution

    |

  19. The correct sequence of correct reagents for the following transformat...

    Text Solution

    |

  20. The addition of silica during the extraction of copper from its sulphi...

    Text Solution

    |