What is the effect of temperature on rate of a reaction.

Explanation

Temperature Coefficient is the ratio of two rates of reactions or rate constants that differ by 10 K.
Temperature coefficient = `("Rate of reaction at 310K")/("Rate of reaction at 300 K")`
For most of the reactions its value is approximately 2. This can be explained as follows.
We know that for the rise in temperature from 300 K to 310 K, the average kinetic energy of the molecules increases by 3% only as it is directly proportional to the temperature. On the other hand, the most reactions, the rate constant doubles i.e., increases by 100% for a `10^@` C rise near room temperature. This can be explained by assuming that certain threshold energy is required for the molecules to react. This is illustrated in figure where the fraction of the colliding molecules possessing different relative energies is plotted.
From the figure it is clear that with the increase in temperature the peak of the curve gets shifted towards the right and the curve at lower temperature. This indicates that the number of molecules with higher energy content have increase with increase in temperature.
The minimum energy (`E_(Th)`) required for the effective collisions is also shown in the diagram and the number of molecules possessing energies equal to on greater than bit, is proportional to area abed at temperature `T_1` and area abef at temperature `T_2`. In the figure, the area abef is roughly twice as large as abcd. Since the rate of reaction depends upon the number of molecules which possess energies higher than threshold energy (for effective collisions), it may be interpreted that the fraction of molecules possessing energy more than threshold energy has increased approximately two times and thereby, increases the rate by two times for a rise in temperature of 10 K.
Thus, we may conclude that increase in the rate of reaction with the rise in temperature is mainly due to the increase in number of effective collisions.