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Write cross aldol condensation....

Write cross aldol condensation.

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Cross-aldol codensation : Aldol condensation between two different aldehydes or ketones, at least one of which contains `alpha`-hydrogen , is called crossed aldol condensation. It is a useful synethetic tool only when one of the aldehyde or ketone does not contain `alpha`-hydrogen. This is because if both the aldehydes or ketones contain `alpha`-hydrogen it gives a mixture of four different products.
For example : condensation between formaldehyde and acetaldehde in the presence of dil NaOH (aq).
`underset("Formaldehyde Acetaldehyde")(H-underset(H)underset(|)overset(O)overset(||)(C)+CH_(3)CHO) overset("Dil.NaoH")rarr underset(beta-"Hydroxypropionaldehyde")(H-underset(H)underset(|)overset(OH)overset(|)(C)-CH_(2)-CHO)underset(-H_(2)O)overset(Delta)rarr underset("Acrolein")(CH_(2)=CH-CHO)`
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Knowledge Check

  • Cross aldol condensation occurs between

    A
    Two same aldehydes
    B
    Two same ketones
    C
    Two different aldehydes and ketones
    D
    None of these
  • Which among the followings undergoes aldol condensation ?

    A
    Methanal
    B
    Benzaldehyde
    C
    Propanal
    D
    None of above
  • Which among the followings undergoes aldol condensation ? Methanal, Benzaldehyde, Propanal or none of the above

    A
    Methanal
    B
    Benzaldehyde
    C
    Propanal
    D
    None of the above
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