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PASSAGE-IV : A neutral organic compound ...

PASSAGE-IV : A neutral organic compound A of molecular formula `C_(2)H_(6)O`, on oxidation with potassium dichromate and sulphuric acid gives an acidic compound B. The compound A reacts with B on warming in presence of conc. `H_(2)SO_(4)` to give a sweet smelling substance C. C on heating with D gives back A.
In the above sequence of reactions compound B is

A

ethanol

B

ethanoic acid

C

ethyl ethanoate

D

water

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The correct Answer is:
To determine the compound B in the given sequence of reactions, we will analyze the information step by step. ### Step-by-Step Solution: 1. **Identify Compound A**: - The molecular formula of compound A is C₂H₆O. - This formula corresponds to an alcohol, specifically ethanol (C₂H₅OH). 2. **Oxidation of Compound A**: - When ethanol (A) is oxidized using potassium dichromate (K₂Cr₂O₇) in the presence of sulfuric acid (H₂SO₄), it forms an acidic compound. - The oxidation of ethanol leads to the formation of acetic acid (ethanoic acid), which has the formula CH₃COOH. 3. **Identify Compound B**: - From the oxidation of ethanol, the acidic compound B is identified as acetic acid (CH₃COOH). 4. **Reaction of A with B**: - When ethanol (A) reacts with acetic acid (B) in the presence of concentrated sulfuric acid and is warmed, an ester is formed. - The reaction produces ethyl acetate (C), which is a sweet-smelling compound. 5. **Formation of Compound C**: - The sweet-smelling substance C is ethyl acetate (CH₃COOC₂H₅). 6. **Heating C with D**: - When ethyl acetate (C) is heated with a compound D, which is sodium hydroxide (NaOH), hydrolysis occurs, leading to the regeneration of ethanol (A) and sodium acetate. ### Conclusion: - Therefore, the compound B in the above sequence of reactions is **acetic acid (ethanoic acid)**, which is represented by the formula CH₃COOH.

To determine the compound B in the given sequence of reactions, we will analyze the information step by step. ### Step-by-Step Solution: 1. **Identify Compound A**: - The molecular formula of compound A is C₂H₆O. - This formula corresponds to an alcohol, specifically ethanol (C₂H₅OH). ...
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MTG IIT JEE FOUNDATION-CARBON AND ITS COMPOUNDS -Comprehension Type
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  2. PASSAGE-I : Diamond and graphite are two allotropic forms of carbon wh...

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  3. PASSAGE-I : Diamond and graphite are two allotropic forms of carbon wh...

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  4. PASSAGE-I : Diamond and graphite are two allotropic forms of carbon wh...

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  5. PASSAGE-II : In all the organic compounds, the four valencies of carbo...

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  6. PASSAGE-II : In all the organic compounds, the four valencies of carbo...

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  7. PASSAGE-II : In all the organic compounds, the four valencies of carbo...

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  8. PASSAGE-II : In all the organic compounds, the four valencies of carbo...

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  9. PASSAGE-III : Structural formmulae of some organic compounds are given...

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  10. PASSAGE-III : Structural formmulae of some organic compounds are given...

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  11. PASSAGE-III : Structural formmulae of some organic compounds are given...

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  12. PASSAGE-III : Structural formmulae of some organic compounds are given...

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  13. PASSAGE-IV : A neutral organic compound A of molecular formula C(2)H(6...

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  14. PASSAGE-IV : A neutral organic compound A of molecular formula C(2)H(6...

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  15. A neutral organic compound A of molecular formula C(2)H(6)O, on oxidat...

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  16. PASSAGE-IV : A neutral organic compound A of molecular formula C(2)H(6...

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  17. PASSAGE-V : In the above sequences of reaction A is

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  18. PASSAGE-V : The compound B is

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  19. PASSAGE-V : In the sequence of reaction C is

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  20. PASSAGE-V : The reagent D is

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