Home
Class 11
CHEMISTRY
An incorrect statement with respect to S...

An incorrect statement with respect to `S_(N)1` and `S_(N)2` mechanism for alkyl halide is:

A

A strong nucleophile in an aprotic solvent increases the rate or favours `S_N2` reaction

B

Competing reaction for an `S_N2` reaction is rearrangement

C

`S_N1` reaction can be catalysed by some Lewis acids

D

A weak nucleophile and a protic solvent increases the rate or favours `S_N1` reaction

Text Solution

Verified by Experts

The correct Answer is:
B

`S_N1` reaction occurs through the formation of carbocation as intermediate. Hence, rearrangement occur in `S_N1`reaction and not in `S_N 2` reaction. `SN_1`reaction is favoured in presence of a polar protic solvent and a weak nucleophile. Astrong nucleophile is an aprotic solvent increases the rate of `S_N2`reaction.
Promotional Banner

Topper's Solved these Questions

  • ISOMERISM AND REACTION MECHANISM

    BRILLIANT PUBLICATION|Exercise LEVEL - III |8 Videos
  • ISOMERISM AND REACTION MECHANISM

    BRILLIANT PUBLICATION|Exercise LEVEL - III (Multiple choice answer type)|15 Videos
  • ISOMERISM AND REACTION MECHANISM

    BRILLIANT PUBLICATION|Exercise LEVEL - III (Linked Comprehension Type) (Paragraph III )|3 Videos
  • HYDROGEN

    BRILLIANT PUBLICATION|Exercise LEVEL -III ( Linked Comprehension Type)|8 Videos
  • ORGANIC CHEMISTRY : SOME BASIC PRINCIPLES - PART I (NOMENCLATURE)

    BRILLIANT PUBLICATION|Exercise LEVEL-III|45 Videos

Similar Questions

Explore conceptually related problems

Most reactive halide towards S_(N)1 reaction is

BRILLIANT PUBLICATION-ISOMERISM AND REACTION MECHANISM-LEVEL-II
  1. Which will undergo fastest S(N)2 substitution reaction when treated wi...

    Text Solution

    |

  2. Under identical conditions, S(N)1 reaction will occur most efficient w...

    Text Solution

    |

  3. Consider the reaction, RCHO+NH(2)NH(2)rarrRCH=N-NH(2). What type of re...

    Text Solution

    |

  4. An incorrect statement with respect to S(N)1 and S(N)2 mechanism for a...

    Text Solution

    |

  5. In which of the following molecules, the resonance effect is not prese...

    Text Solution

    |

  6. For 1-methoxy-1, 3-butadiene, which of the following resonating struct...

    Text Solution

    |

  7. Which of the following statements regarding resonance is not correct?

    Text Solution

    |

  8. Amongst the given species, the best leaving group in a nucleophilic su...

    Text Solution

    |

  9. The mechanism of the reaction between tert-butyl alcohol and hydroxide...

    Text Solution

    |

  10. In which of the following pairs A is more stable than B?

    Text Solution

    |

  11. Which of the following carbocations will not rearrange?

    Text Solution

    |

  12. Which one of the following substitutents at para-position is most effe...

    Text Solution

    |

  13. The order of decreasing ease of abstraction of hydrogen atoms in the f...

    Text Solution

    |

  14. Which of the following reactions involves a nucleophile? (I) CH(3)CO...

    Text Solution

    |

  15. In the following carbocation, H//CH(3) that is most likely to migrate...

    Text Solution

    |

  16. The hyperconjugative stabilities of tert-butyl cation and 2-butene, re...

    Text Solution

    |

  17. If the carbocation rearranges to gain stability, it will rearrange to

    Text Solution

    |

  18. p-chlorophenol is a stronger acid than phenol because

    Text Solution

    |

  19. The major product in the reaction is:

    Text Solution

    |

  20. Consider the following compounds: Hyperconjugation occurs in

    Text Solution

    |