Home
Class 12
CHEMISTRY
The amine which can react with C6 H5 -SO...

The amine which can react with `C_6 H_5 -SO_2 -Cl` to form a product insoluble in alkali shall be

A

Primary amine

B

Secondary amine

C

Tertiary amine

D

Both primary and secondary amines

Text Solution

Verified by Experts

The correct Answer is:
B

`C_6 H_5 SO_2 Cl` is called Hinsberg.s reagent which reacts with sec amine to form a product insoluble in alkalies. This reaction is used to separate `1^@, 2^@ and 3^@` amines from their mixture.
Promotional Banner

Topper's Solved these Questions

  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-II|48 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Single Correct Answer Type)|7 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise (Leve-2)|24 Videos
  • HALOALKANES AND HALOARENES

    BRILLIANT PUBLICATION|Exercise Level-II|37 Videos
  • NUCLEAR CHEMISTRY

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Linked Comprehension Type) |11 Videos

Similar Questions

Explore conceptually related problems

C_6H_5COCH_3 is not formed in

Give the structure of A (C 3 ​ H 9 ​ N) if it reacts with benzene sulphonyl chloride to form a solid insoluble in alkali.

When 2-butyne is treated with dil H_2 SO_4 HgSO_4 the product formed is

When neo-pentyl alcohol is reacted with conc H_(2)SO_(4) , the major product formed is

NaCl+H_(2)SO_(4)rarrNaHSO_(4)+HCl a) In the above reaction, NaCl reacts with H_(2)SO_(4) and form, hydrochloric acid. Similarly, which salt react with H_(2)SO_(4) to form nitric acid? b) Write the chemical equation.

What is the product when Mg react with SO_(2) ?

An amine reacts with benzene sulphonyl chloride to form a white precipitate which is insoluble in aq. NaOH. The amine is

The aqueous solution of a nitrogen and chlorine containing organic compound (A) is acidic to litmus. (A) on treatment with aqueous NaOH, it gives a compound (B) containing nitrogen, but not chlorine. Compound (B) on treatment with C_6 H_5SO_2 Cl in the presence of NaOH gives an insoluble product (C) C13H13NO2 S. Give the structures of (A) and (B).

Ethanol when reacted with PCl_5 gives A, POCl_3 and HCl. A reacts with AgNO_2 to form B as major product and AgCl . A and B respectively are?

1.5 g of H_2 react with 14.5 g of O_2 to form water Which is the limiting reagent?

BRILLIANT PUBLICATION-NITROGEN COMPOUNDS-LEVEL-I
  1. Which of the following statements about primary amines is 'False'?

    Text Solution

    |

  2. Which of the following reacts with chloroform and a base to form pheny...

    Text Solution

    |

  3. The amine which can react with C6 H5 -SO2 -Cl to form a product insolu...

    Text Solution

    |

  4. Among the following compounds C3 H7 NH2 , NH3 ,CH3 NH2, and C6 H5 NH2...

    Text Solution

    |

  5. Which one of the following on reduction with lithium aluminium hydride...

    Text Solution

    |

  6. The reduction of nitro compounds is most preferred in the presence of

    Text Solution

    |

  7. Ethyl isocyanide on hydrolysis in acidic medium generates

    Text Solution

    |

  8. Which of the following gives propylamine upon hydrolysis? : CH3 CH2 ...

    Text Solution

    |

  9. Select the incorrect statement.

    Text Solution

    |

  10. Cope elimination is an intramolecular E2 reaction because : It is giv...

    Text Solution

    |

  11. Which is most volatile?

    Text Solution

    |

  12. Which has maximum boiling point? :

    Text Solution

    |

  13. The product formed by the reaction of acetamide with bromine in the pr...

    Text Solution

    |

  14. Acetamide and ethyl amine are distinguished by reacting with

    Text Solution

    |

  15. The reaction in which primary amine is not formed

    Text Solution

    |

  16. Which of these alkyl halides can be used to prepare amines using Gabri...

    Text Solution

    |

  17. Which one of the following methods is neither meant for the synthesis ...

    Text Solution

    |

  18. Considering the basic strength of amines in aqueous solution, which on...

    Text Solution

    |

  19. In the chemical reaction, CH 3 ​ CH 2 ​ NH 2 ​ + CHCl 3 ​ ...

    Text Solution

    |

  20. The final product formed when ethyl amine is treated with NaNO2 and HC...

    Text Solution

    |