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In the chemical reaction, CH 3 ​ CH ...

In the chemical reaction, CH 3 ​ CH 2 ​ NH 2 ​ + CHCl 3 ​ + 3KOH → (A) + (B) + 3H 2 ​ O, the compounds(A) and (B) are respectively :

A

`C_2 H_5 CN and 3KCl`

B

`CH_3 CH_2 CONH_2 and 3KCl`

C

`C_2 H_5 NC and K_2 CO_3`

D

`C_2 H_5 NC and 3KCl`

Text Solution

Verified by Experts

The correct Answer is:
D
Primary amines react with chloroform and alkali metal hydroxide to give carbylamine (isonitrile) reaction.
`CH_3-CH_2 -NH_2 + CHCl_3 + 3KOH to C_2 H_5 -Noverset(to)= C+3KCl+ 3H_2 O`
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