Home
Class 12
CHEMISTRY
Rank the following compounds in terms of...

Rank the following compounds in terms of their relative reactivity in nitration.

A

`IV gt II gt III gt I gt V`

B

`V gt I gt III gt II gt IV`

C

`III gt II gt IV gt I gt V`

D

`V gt I gt IV gt II gt III`

Text Solution

Verified by Experts

The correct Answer is:
B

V is most reactive due to electron donating resonance effect of`-OCH_3` . I is second most reactive due to electron donating inductive effect of`-CH_3`. IV is least reactive due to positive charge on nitrogen Mitrobenzene is less reactive than chlorobenzene due to stronger electron withdrawing effect by`-NO`
Promotional Banner

Topper's Solved these Questions

  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Single Correct Answer Type)|7 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Multiple Choice Answer Type)|12 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-I|50 Videos
  • HALOALKANES AND HALOARENES

    BRILLIANT PUBLICATION|Exercise Level-II|37 Videos
  • NUCLEAR CHEMISTRY

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Linked Comprehension Type) |11 Videos

Similar Questions

Explore conceptually related problems

Arrange the following compounds in the increasing order of their reactivity in nucleophilic addition reaction A) Acetophenone B) Benzaldehyde C) Formaldehyde D) Acetone

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. (i) Ethanal, propanal, propanone, butanone

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. (ii) Benzaldehyde, P-Tolualdehyde, P-Nitrobenzaldehyde Acetophenone

Arrange the following set of compounds in order of thelr decreasing relative reactivity with an electrophile, E^+ a. Chlorobenzene, 2,4 -dinitrochlorobenzenè, p nitrochlorobenzene b. Toluene, p-C H_3 -C_6 H_4-NO_2, p-O_2 N-C_6 H_4-N O_2

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reaction. i. Ethanal, Propanal, Propanone, Butanone ii. Benzaldehyde, p - Tolualdehyde, p -Nitrobenzaldehyde, Ácetophẹnone (Hint: Consider' steric effect and electronic effect).

Arrange the following compounds in the order of reactivity with alcoholic silver nitrate, C_(6)H_(5)CH_(2)CH_(2)Br (I), C_(6)H_(5)CHBrCH_(3)(II) and C_(6)H_(5)CH = CHBr (III)

BRILLIANT PUBLICATION-NITROGEN COMPOUNDS-LEVEL-II
  1. Which is the starting reagent used to make the given azo compound?

    Text Solution

    |

  2. Choose the reaction sequence that could be used in the following tranf...

    Text Solution

    |

  3. Rank the following compounds in terms of their relative reactivity in ...

    Text Solution

    |

  4. The aromatic heterocyclic base pyridine is sulphonated by heating with...

    Text Solution

    |

  5. In which of the following compounds is there the least delocalization ...

    Text Solution

    |

  6. Give the reagents that will best accomplish the following transformati...

    Text Solution

    |

  7. Which of the following statements is/are true about amines?

    Text Solution

    |

  8. Arrange the following structure of quaternary salt in the decreasing o...

    Text Solution

    |

  9. Which of the following statements are correct? 1.In Sandmeyer reacti...

    Text Solution

    |

  10. Indicate which nitrogen compound amongst the following would undergo H...

    Text Solution

    |

  11. Reagents capable of converting cyclohexanone to N-ethyl cyclohexylamin...

    Text Solution

    |

  12. Which has the highest value of pkb ?

    Text Solution

    |

  13. C4 H(11) N on reaction with HNO2 forms tertiary alcohol. Thus, C4 H(11...

    Text Solution

    |

  14. Text Solution

    |

  15. Hofmann's elimination product of

    Text Solution

    |

  16. Basic nature of the following is in order

    Text Solution

    |

  17. The major products from the following sequence of reactions are (CH...

    Text Solution

    |

  18. What is the product of the following reaction?

    Text Solution

    |

  19. The reaction of chloroform with alcoholic KOH and p-toluidine forms

    Text Solution

    |

  20. In the chemical reaction the compounds A and B, respectively are

    Text Solution

    |