Home
Class 12
CHEMISTRY
Indicate which nitrogen compound amongst...

Indicate which nitrogen compound amongst the following would undergo Hoffmann bromamide reaction to furnish the primary amine `(R-NH_2)`.

A

`RCONHCH_3`

B

`RCOONH_4`

C

`RCONH_2`

D

`R-CO-NHOH`

Text Solution

Verified by Experts

The correct Answer is:
C

Only `1^@` amides (i.e. `RCONH_2`) in the present case undergo Hofmann bromamide reaction.
`RCONH_2 + Br_2 + 4KOH to R- NH_2 + 2KBr + K_2 CO_3 + 2H_2 O` (Hofmann.s bromamide reaction)
Promotional Banner

Topper's Solved these Questions

  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Single Correct Answer Type)|7 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Multiple Choice Answer Type)|12 Videos
  • NITROGEN COMPOUNDS

    BRILLIANT PUBLICATION|Exercise LEVEL-I|50 Videos
  • HALOALKANES AND HALOARENES

    BRILLIANT PUBLICATION|Exercise Level-II|37 Videos
  • NUCLEAR CHEMISTRY

    BRILLIANT PUBLICATION|Exercise LEVEL-III (Linked Comprehension Type) |11 Videos

Similar Questions

Explore conceptually related problems

Which of the following can not give Hoffmann's bromamide reaction:

Which of the following compounds will give Hofmann bromamide reaction

Which one of the following compounds would undergo Cannizaro reaction?

Which of the following cannot undergo E2 reaction ?

Which of the following compounds undergo nuclephilic substitution reactions?

Which compound in each of the following pairs will react faster in S_N2 reaction with overset(Theta)OH .

Which of the following compounds would undergo aldol condensation, or Cannizaro reaction ? Benzaldehyde.

Which of the following compounds would undergo aldol condensation, or Cannizaro reaction ? Benzophenone.

Which of the following compounds would undergo aldol condensation, or Cannizaro reaction ? Methanal.

In each of the following pairs of compounds, identify the compound which will undergo SN1 reaction faster?

BRILLIANT PUBLICATION-NITROGEN COMPOUNDS-LEVEL-II
  1. Arrange the following structure of quaternary salt in the decreasing o...

    Text Solution

    |

  2. Which of the following statements are correct? 1.In Sandmeyer reacti...

    Text Solution

    |

  3. Indicate which nitrogen compound amongst the following would undergo H...

    Text Solution

    |

  4. Reagents capable of converting cyclohexanone to N-ethyl cyclohexylamin...

    Text Solution

    |

  5. Which has the highest value of pkb ?

    Text Solution

    |

  6. C4 H(11) N on reaction with HNO2 forms tertiary alcohol. Thus, C4 H(11...

    Text Solution

    |

  7. Text Solution

    |

  8. Hofmann's elimination product of

    Text Solution

    |

  9. Basic nature of the following is in order

    Text Solution

    |

  10. The major products from the following sequence of reactions are (CH...

    Text Solution

    |

  11. What is the product of the following reaction?

    Text Solution

    |

  12. The reaction of chloroform with alcoholic KOH and p-toluidine forms

    Text Solution

    |

  13. In the chemical reaction the compounds A and B, respectively are

    Text Solution

    |

  14. Which of the following is the correct statement about coupling reactio...

    Text Solution

    |

  15. Identify the end product Z in the following sequence. C6 H5 NH2 ...

    Text Solution

    |

  16. Arrange the following amines in order of increasing basicity (least to...

    Text Solution

    |

  17. Aniline is treated with bromine water and the resulting product is tr...

    Text Solution

    |

  18. In the above sequence, II is

    Text Solution

    |

  19. Determine the end product of the following reactions C2 H5 NH2 over...

    Text Solution

    |

  20. Benzylamine may be alkylated as shown in the following equation: C6...

    Text Solution

    |