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The correct statement regarding the basi...

The correct statement regarding the basicity of arylamines is

A

arylamines are generally more basic than alkylamines because of aryl group.

B

arylamines are generally more basic than alkylamines because the nitrogen atom in alkylamines is sp-hybridised.

C

arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalised by interaction with the aromatic ring `pi`-electron system

D

arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalised by interaction with the aromatic ring `pi`-electron system.

Text Solution

Verified by Experts

The correct Answer is:
C

Due to nitrogen lone pair of electrons are delocalized by interaction with the aromatic ring `pi`-electrons.
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BRILLIANT PUBLICATION-NITROGEN COMPOUNDS-LEVEL-II
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  2. Which of the following methods of preparation of amines will not give ...

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  3. The product 'Y' in the following reaction sequence is

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  4. Which one of the following nitro-compounds does not react with nitrous...

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  6. In a set of reactions, m-bromobenzoic acid gave a product D. Identify ...

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  7. The correct statement regarding the basicity of arylamines is

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  8. An organic compound 'A' on reduction gives compound 'B' which on react...

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  9. Although amino group ls-o- and p- directing in aromatic electrophilic ...

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  10. The correct sequence of reactions to be performed to convert benzene i...

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  11. An amine reacts with benzene sulphonyl chloride to form a white precip...

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  12. When propane is subjected to the treatment with fuming nitric acid at ...

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  13. A nitrogenous substance (X) is treated with HNO, and the product so fo...

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  14. Which of the following reactions does not yield an amine?

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  15. The following reaction is:

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  16. An amine on treatment with HNO2 evolved N2 . The amine on exhaustive m...

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  17. Reaction of cyclohexanone with dimethylamine in the presence of cataly...

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  18. Which gives black precipitate on reaction with CS2 followed by additio...

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  19. Which among the following amines can be directly oxidised to the corre...

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  20. Which of the following compounds will dissolve in an alkali solution a...

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