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Among [Ni (CO)4], [Ni(CN)4]^(2-), [NiCl4...

Among `[Ni (CO)_4], [Ni(CN)_4]^(2-), [NiCl_4]^(2-)` species, the hybridisation states at the Ni atom are, respectively (Atomic number.of Ni=28)

A

`sp^3, dsp^2, dsp^2`

B

`sp^3, dsp^2, sp^2`

C

`sp^3, sp^3,dsp^2`

D

`dsp^2, sp^3, sp^3`

Text Solution

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The correct Answer is:
B

`[NiCl_4]^(2-) to sp^3` hybridisation `to `tetrahedral `[Ni(CO)_4] to sp^3` hydridisation `to` tetrahedral
`[Ni(CN)_4]^(2-) to dsp^2` hybridisation `to` square planar
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BRILLIANT PUBLICATION-COORDINATION COMPOUNDS -LEVEL I
  1. Which one of the following complex ions has geometrical isomers?

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  2. Which of the following complex species is not expected to show optical...

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  3. Among [Ni (CO)4], [Ni(CN)4]^(2-), [NiCl4]^(2-) species, the hybridisat...

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  4. The pair having the same magnetic moment is : (Atomic Nos : Cr=24, M...

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  5. Hybridization, shape and magnetic moment of K3[Co(CO)3] is

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  6. Which one of the following is an outer orbital complex and exhibits pa...

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  7. Which one of the following is wrongly matched?

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  8. Geometrical shape of the most stable complexes formed by the reaction ...

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  9. The low spin complex of d^(6) metal ion in an octahedral field will ha...

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  10. Which ofthe following complexions is expected to absorb visible light?

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  11. [Cr(H(2)O)(6)]Cl(3) has a spin only magnetic moment of 3.83BM. The cor...

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  12. Among the following complexes, the one which shows zero CFSE is (Ato...

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  13. EAN of cobalt is 36 in [Co(NH3)2 O2 (en)Cl]. Knowing that atomic numbe...

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  14. Fe2(CO)9 is diamagnetic. Which of the following is the correct reason?...

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  15. Among the following metal carbonyls, the C–O bond order is lowest in

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  16. Which of the following complexes is used as an anti-cancer agent?

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  17. Sodium nitroprusside reacts with sulphide ion to give a purple colour ...

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  18. Find the ligand having the highest denticity from the following option...

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  19. Which of the following ligands is tridentate type?

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  20. Which of the following complex has highest EAN value?

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