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Amongst Ni (CO)4, [Ni(CN)4]^(2-) and [Ni...

Amongst `Ni (CO)_4, [Ni(CN)_4]^(2-)` and `[NiCl_4]^(2-)`

A

`Ni(CO)_4 and [NiCl_4]^(2-)` are dimagnetic and `[Ni(CN)_4]^(2-)` is paramagnetic

B

`[NiCl_4]^(2-) and [Ni(CN)_4]^(2-)` are diamagnetic and `Ni(CO)_4` is paramagnetic

C

`Ni(CO)_4 and [Ni(CN)_4]^(2-)` are diamgnetic and `[NiCl_4]^(2-)` is paramagnetic

D

`Ni(CO)_4 and [Ni(CN)_4]^(2-)` are diamagnetic and `[NiCl_4]^(2-)` is paramgnetic

Text Solution

Verified by Experts

The correct Answer is:
C

`[Ni(CO)_4] and [Ni(CN)_4]^(2-)` do not contain any unpaired electron while `[NiCl_4]^(2-)` contains two unpaired electrons.
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