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Using MOT, which of the following pairs ...

Using MOT, which of the following pairs denote paramagnetic species?

A

`B_(2) and C _(2)`

B

`B _(2) and O _(2)`

C

`N _(2) and C _(2)`

D

`O _(2) and O _(2) ^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

Among given four pairs, `B _(2) and O _(2)` are paramagnetic due to presence of unpaired electron.
`MO (EC) of B _(2) = sigma 1 s ^(2) sigma ^(**) 1 s ^(2) pi 2p _(2) ^(1) -= pi 2 p _(y) ^(1)`
`MO (EC) of O _(2) = sigma 1 s ^(2) sigma ^(**) 1s ^(2) sigma 2s ^(2)sigma ^(**) 2s ^(2) sigma 2 p _(2) pi 2p _(x) ^(2) -= pi 2p _(y) ^(2) pi ^(**) 2 p _(x) ^(1) -= pi 2 p _(y) ^(1)`
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