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The spin-only magn etic moment value of ...

The spin-only magn etic moment value of `B_2^(+)` species is __________` xx 10^(-2)` BM. (Nearest integer)
[Given : `sqrt3 = 1.73`]

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To solve the problem of finding the spin-only magnetic moment value of the \( B_2^+ \) species, we will follow these steps: ### Step 1: Understand the Formula for Spin-Only Magnetic Moment The formula for the spin-only magnetic moment (\( \mu \)) is given by: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ### Step 2: Determine the Electron Configuration of \( B_2^+ \) The atomic number of boron (B) is 5. Therefore, the molecular formula \( B_2 \) has a total of 10 electrons. Since we are dealing with \( B_2^+ \), we need to remove one electron, leaving us with 9 electrons. ### Step 3: Fill the Molecular Orbitals According to molecular orbital theory, the filling order for the first 10 electrons in \( B_2 \) is as follows: 1. \( \sigma_{1s} \) - 2 electrons 2. \( \sigma_{1s}^* \) - 2 electrons 3. \( \sigma_{2s} \) - 2 electrons 4. \( \sigma_{2s}^* \) - 0 electrons 5. \( \pi_{2p_x} \) - 2 electrons 6. \( \pi_{2p_y} \) - 2 electrons 7. \( \sigma_{2p_z} \) - 0 electrons For \( B_2^+ \) (9 electrons), the filling will be: 1. \( \sigma_{1s} \) - 2 electrons 2. \( \sigma_{1s}^* \) - 2 electrons 3. \( \sigma_{2s} \) - 2 electrons 4. \( \sigma_{2s}^* \) - 0 electrons 5. \( \pi_{2p_x} \) - 2 electrons 6. \( \pi_{2p_y} \) - 1 electron (since we have 9 electrons total) ### Step 4: Count the Unpaired Electrons From the filling, we see that in the \( \pi_{2p_x} \) and \( \pi_{2p_y} \) orbitals, there is one unpaired electron in \( \pi_{2p_y} \). Therefore, \( n = 1 \). ### Step 5: Calculate the Spin-Only Magnetic Moment Now, substituting \( n = 1 \) into the formula: \[ \mu = \sqrt{1(1 + 2)} = \sqrt{3} \] ### Step 6: Convert to the Required Units The value of \( \sqrt{3} \) is approximately 1.73. Since the problem asks for the answer in \( \times 10^{-2} \) BM, we convert it: \[ \mu = 1.73 \, \text{BM} = 173 \times 10^{-2} \, \text{BM} \] ### Final Answer Thus, the spin-only magnetic moment value of \( B_2^+ \) species is: \[ \boxed{173} \]
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