Which of the following will not give Hof...

Which of the following will not give Hoffmann bromamide reaction?

`CH_(3)-overset(O)overset(||)C-NH_(2)`

`Ph-overset(O)overset(||)C-NH_(2)`

`CH_(3)-overset(O)overset(||)C-NH-Br`

`Ph-overset(O)overset(||)C-NH-Ph`

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The correct Answer is:

`Ph-overset(O)overset(||)C-NH-Ph`
N-substituted amide will not undergo Hoffmann bromamide reaction because formation of iso-cyanate is not possible.

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