By how much is the oxidizing power of `Cr_2O_7^(2-)"|"Cr^(3+)` couple decreased if the `H^+` concentration is decreased from 1M to `10^(-30`M at `25^(@)` C?
A
0.001 V
B
0.207 V
C
0.441 V
D
0.414 V
Text Solution
Verified by Experts
The correct Answer is:
D
Topper's Solved these Questions
ELECTROCHEMISTRY
NARENDRA AWASTHI|Exercise Level 1 (Q.1 To Q.30)|1 Videos
ELECTROCHEMISTRY
NARENDRA AWASTHI|Exercise Level 1 (Q.91 To Q.120)|1 Videos
DILUTE SOLUTION
NARENDRA AWASTHI|Exercise Level 3 - Match The Column|1 Videos
Calculate the oxidation number in Cr_2O_7^-2 ion on chromium (Cr) atom.
The charge required for the reduction of 0.4 mol of K_2Cr_2O_7 to Cr^(3+) ions is
In the conversion of K_(2)Cr_(2)O_(7) to K_(2)CrO_(4) the oxidation number of the following changes
In the conversion of K_(2)Cr_(2)O_(7) to K_(2)CrO_(4) the oxidation number of the following changes
In a first order reaction, the concentration of the reactant decrease from 0.6 M to 0.3 M in 15 min. The time taken for the concentration to change from 0.1 M to 0.025 M in minutes is
What are the oxidation of Cr in CrO_(3) and Ti in H_(2)TiO_(4) ?
In a first order reaction, the concentration of the reactant, decreases from 0.8 M to 0.4 M in 15 minutes. The time taken for the concentration to hange from 0.1 M to 0.025 M is
K_2Cr_2O_7 acts as a good oxidizing agent in acidic medium underset("Orange")(Cr_(2)O_(7)^(2-)) + 14H^(+) + 6e^(-) rarr underset("Green")(2Cr^(3+)) + 7H_2O In alkaline solution, orange colour of Cr_(2)O_(7)^(2-) chages to yellow colour due to formation of Cr_2O_(4)^(2-) and again yellow colour changes to orange colour on changing the solution to acidic medium underset("Orange")(Cr_2O_7^(2-))+2OH^(_) rarrunderset("Yellow")(Cr_2O_7^(2-))+H_2O underset("Yellow")(2CrO_(4)^(2_-)) + 2H^(+) rarr underset("Orange")(Cr_(2)O_(7)^(2-) + H_(2)O) Cr_(4)^(2-) and Cr_(2)O_(7)^(2-) exist in equilibrium at pH =4 and are interconvertible by altering the pH of the solution. When heated with H_2SO_4 and metal chloride K_2Cr_2O_7 gives vapour of chromyl chloride (CrO_2Cl_2) . Chromyl chloride (CrO_2Cl_2) when passed into aqueous NaOH solution, yellow colour solution of CrO_(4)^(2-) is obtained. This on reaction with lead acetate gives yellow ppt. PbCrO_4 . When H_2O_2 is added to an acidified solution of dichromate ion, a complicated reaction occurs. The products obtained depend on the pH and concentration of dichromate. Cr_2O_7^(2-)+2H^(+) + 4H_(2)O_(2) rarr 2Cr(O_2)+5H_2O A deep blue-violet coloured peroxo compound, CrO(O_2)_2, ' called chromic peroxide is formed. This decomposes rapidly in aqueous solution into Cr^(3+) and xygen. CrO_3 on reaction with HCl and the product on reaction with NaOH(aq) give respectively