Home
Class 11
CHEMISTRY
The cell potential (E(cell)) of a reacti...

The cell potential `(E_(cell))` of a reaction is related as `/_\G=-nF E_(cell)`, where `/_\G` represents max. useful electrical work
n=no. of moles of electrons exchanged during the section
for reversible cell reaction `d(/_\G)=(/_\_rV)dp-(/_\_rS),dT`
at constant pressure `d(/_\G)=-(/_\_rS).dT`
:' At constant pressure `/_\G``=/_\H-T./_\S`
:. `/_\G``=/+\-H+T(d(/_\G))/((dT)_P)`
`((dE_(cell))/(dT))_P` is known as temperture coefficient of the e.m.f of the cell.
Calculate `/_\S` for the given cell reaction in Q. no. 2:

A

-73.53J/Kmol

B

83.53J/Kmol

C

100J/Kmol

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    NARENDRA AWASTHI|Exercise Level 1 (Q.1 To Q.30)|1 Videos

  • ELECTROCHEMISTRY

    NARENDRA AWASTHI|Exercise Level 1 (Q.91 To Q.120)|1 Videos

  • DILUTE SOLUTION

    NARENDRA AWASTHI|Exercise Level 3 - Match The Column|1 Videos

  • GASEOUS STATE

    NARENDRA AWASTHI|Exercise Level 3 - Subjective Problems|1 Videos

Similar Questions

Explore conceptually related problems

The cell potential (E_("cell")) of a reaction is related as DeltaG = -nFE_("cell") , where DeltaG represents max. useful electrical work . n=no. of moles of electrons exchanged during the reactino of reversible cell reaction d(DeltaG) = (DeltaV)dP-(DeltaS).dT at constant pressure d(DeltaG) = - (DeltaS).dT :' At constant pressure DeltaG = DeltaG = DeltaH-TDeltaS .......(1) :. DeltaG = DeltaH + T((d(DeltaG))/(dT))_P ......... (B) ((dE_("cell"))/(dT))_(P) is known as temperature coefficient of the e.m.f of the cell When DeltaS increases, temperature coefficient of the emf of cell

DeltaG = DeltaH-TdeltaS and DeltaG = DeltaH + T[(d(DeltaG))/(dT)] " then " ((dE_("cell"))/(dT)) is

How is E^(0) cell related mathematically to the equilibrium constant K_(c) of the cell reaction ?

How is Gibbs energy (G) related to the cell emf (E) mathematically ?

The number of unit cells in 58.5 g of NaCl is approximately

In an electrochemical cell Delta G= Delta H

Which of the indicated relationship is correct for the following exothermic reaction carried out at constant pressure? CO_((g)) + 3H_(2(g)) rarr CH_(4(g)) + H_(2)O_((g))

For a spontaneous reaction the DeltaG , equilibrium constant (K) and E_("cell")^(0) will be respectively .

What is G_(0) (quiescent phase) of cell cycle?