Home
Class 11
CHEMISTRY
What is the compressibility facto (Z) fo...

What is the compressibility facto (Z) for 0.02 mole of a van der Waal's gas at pressure of 0.1 atm. Assume the size of gas molecules is neligible.
Given : RT = 20 L. atm `"mol^(-1)` and `alpha` = 1000 atm `L^(2) "mol^(-2)`

A

2

B

1

C

0.02

D

0.5

Text Solution

Verified by Experts

The correct Answer is:
d

(d) `(0.1+(1000xx(0.02)^(2))/(V^(2)))V=20xx0.02`
`=0.1V^(2)-0.4V+0.4=0`
`=V^(2)-4V+4=0`
`implies" "V=2L`
`Z=(PV)/(nRT)=(0.1xx2)/(20xx0.02)=0.5`
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    NARENDRA AWASTHI|Exercise Level 1 (Q.31 To Q.60)|1 Videos
  • GASEOUS STATE

    NARENDRA AWASTHI|Exercise Level 1 (Q.121 To Q.150)|1 Videos
  • ELECTROCHEMISTRY

    NARENDRA AWASTHI|Exercise Level 3 - Subjective Problems|1 Videos
  • IONIC EEQUILIBRIUM

    NARENDRA AWASTHI|Exercise Assertin-Reason Type Questions|1 Videos

Similar Questions

Explore conceptually related problems

The compression factor (compressibility factor) for one mole of a van der Waals gas at 0°C and 100 atmospheric pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the van der Waals constant a.

At 27^@C , one mole of an ideal gas exerted a pressure of 0.821 atmospheres. What is its volume in litres ? (R = 0.082 "lit-atm/mol"^(-1) K^(-1))

The temperature of 5 moles of a gas is decreased by 2K at constant pressure of 1 atm. Indicate the correct statement

The compression factor for one mole of real gas at 0^@C and 100 atm is 0.5. Calculate the van der Waals' constant 'a', if 'b' is zero.

For a van der Waal's gas, determine Boyle Temperature (given a = 4.5 atm L^2 mol^(-2) , b = 0.9 L mol^(-1) and R = 0.082 L atm K^(-1) mol^(-1) ]

What is the density of N_2 gas at 227^@ C and 5.00atm. pressure? (R = 0.082 L atm K^(-1) mol^(-1))

A vessel of 25 litre capacity contains 10 moles of steam under pressure of 50.3 atm. Calculate the temperature of steam using van der Waals equation (if for water a=5.46 bar L^2 mol^(-2) and b=0.031 L mol^(-1) )

If 1.5 L of an ideal gas at a pressure of 20 atm expands isothermally and reversibly to a final volume of 15 L the work done by the gas in L atm is