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A 5. 25% solution of a non-electrolyte i...

A 5. 25% solution of a non-electrolyte is isotonic with a 1. 5% solution of urea (molar mass = 60 g `mol^(-1)`) in the same solvent. If the densities of both the solution are assumed to be equal to 1 g `cm^(-3)` , than molar mass of nonelectrolyte substance will be:-

A

115 g `mol^(-1)`

B

105 g `mol^(-1)`

C

210 g `mol^(-1)`

D

90 g `mo1^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

Assume 100 ml solution in both cases, `therefore` for 5. 25% `W/v` &1. 5% `W/v` & `pi_1` = `pi_2`
`implies(5.25)/(M_W)=(1.5)/(60)`
`rArrM_W=(5.25xx60)/(1.5)=5.25xx40=210g`
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