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The following is not an appropriate reac...

The following is not an appropriate reaction for the preparation of t-butyl ethyl ether.
`C_(2)H_(5)ONa+CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-Cl rarr CH_(3)-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-OC_(2)H_(5)`
(i) What would be the major product of this reaction ?
(ii) Write a suitable reaction for the preparation of t-butylethyl ether.

A

`l-CH_(2)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)-CH_(2)-Cl`

B

`Cl-CH_(2)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)-CH_(2)-l^(-)`

C

`H_(2)C=overset(CH_(3))overset(|)C-CH_(2)-CH_(2)=Cl`

D

`Cl-CH_(2)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-CH_(2)=CH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

`S_(N^2)` reaction is favourable at least crowded site
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The following is not an appropriae reaction for the preparation of t-butyl ethyl ether. C_(2)H_(5)ONa+CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-Cl to CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OC_(2)H_(5) i) What would be the major product of this reaction ? ii) Write a suitable reaction for the preparation of t-butylethyl ether

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