Home
Class 12
CHEMISTRY
Nucleophilic Aromatic substitution (SN(A...

Nucleophilic Aromatic substitution `(SN_(Ar))` :
A substituted benzene derivative containing-`NO_2` and Cl group at p-position is subjected to Nu-substitution.

Match the column I and II :

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

Mesenhemier complex is more stable by strong -I group.
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS

    MS CHOUHAN|Exercise LEVEL-2 (SUBJECTIVE PROBLEMS)|3 Videos
  • AROMATIC COMPOUNDS

    MS CHOUHAN|Exercise LEVEL-2|11 Videos
  • AMINES

    MS CHOUHAN|Exercise Level-2|1 Videos
  • BIOMOLECULES

    MS CHOUHAN|Exercise LEVEL - 2|5 Videos

Similar Questions

Explore conceptually related problems

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons. Identify the incorrect statement

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons. Major products of nitration of acetanilide is:

Electrophilic substitution on mono substituted benzene is determined by electronic effects +1, -M groups are ortho, para directors, where as -1,-M groups are meta directions. When there is a competition between inductive and mesomeric effects, the latter wins over. Electrophilic substitution on disubstituted benzene is determined by the combined effect of both groups. Usually activating group wins over deactivating group. When one of the groups has a lone pair of electrons, that will determine the product formation. Usually a third group will not enter the position in between the two existing groups due to steric reasons.

Electron withdrawing groups in benzene ring facilitate nucleophilic substitution. Substantiate

The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) The reaction of toluene with Cl_2 in presence of FeCl_3 gives predominantly:

The typical reaction of benzene and other aromatic compounds is electrophilic substitution. Presence of electron donating group activates the ring towards electrophilic substitution, while presence of electron withdrawing group deactivates the ring towards electrophilic substitution but at the same time activates the ring towards nucleophilic substitution. Some groups are predominantly meta directing and all of these are deactivating. Except halogen, most of the o- and p- directing groups are activating groups. (E.A.S = Electrophilic aromatic substation) Presence of nitro group in benzene ring:

Discuss the effect of nitro group in chloro benzene towards nucleophilic substitution reaction.

A group which deactivates the benzene ring towards electrophilic substitution but directs the incoming group towards o - and p- positions is

The nucleophilic substitution reactions taking place in aromatic system are designated as SN Ar In fact aryl halides do not easily undergo nucleophilic substitution under ordinary conditions. However, introduction of electron- withdrawing groups in o, p – positions makes the reaction to go faster. Keeping these general points in view answer the following questions product. The solution is treated with AgNO_3 solution. Which of the following is correct