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pK(b) of aniline is more than that of me...

`pK_(b)` of aniline is more than that of methylamine. Why?

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Account for the following: (i) pK_(b) of aniline is more than that of methylamine. (ii) Ethylamine is soluble in water whereas aniline is not. (iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide. (iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline. (v) Aniline does not undergo Friedel-Crafts reaction. (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.

Aniline is more basic than

Aniline is less/more basic than ethylamine.

K_(b) of p-methylaniline is more / less than aniline.

XII BOARDS PREVIOUS YEAR-QUESTION PAPER 2022 TERM 2 SET 2-SECTION B
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  4. Write differences between physisorption and chemisorption.

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  8. Which of the following statement(s) is/are correct? (A) Transition m...

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  9. Zn, Cd, Hg are soft and have low melting point. Explain

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  10. pK(b) of aniline is more than that of methylamine. Why?

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  11. Aniline does not undergo Friedel Crafts alkylation. Explain.

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  12. State reasons for the following: primary amines have higher boiling po...

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  13. Arrange the following in the increasing order of their basic strength ...

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  14. What is Hinsberg's reagent ?

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  15. What is the role of pyridine in the acylation reaction of amines ?

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  16. A compound 'A' on reduction with iron scrap and hydrochloric acid give...

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  17. Complete the following CH(3)CN. overset((1.AIH(i-Bu)(2)))underset(2....

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  18. Complete the following Write IUPAC name of the following compound .

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