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The correct decreasing order of first io...

The correct decreasing order of first ionisation enthalpies of five elements of second period is

A

`Be gt B gt C gt N gt F`

B

`N gt F gt C gt B gt Be`

C

`F gt N gt C gt Be gt B`

D

`N gt F gt B gt C gt Be`

Text Solution

Verified by Experts

The correct Answer is:
C

As we move along the period, the nuclear charge increases and size of atom decreases. Therefore, it is more difficult to remove electron from an atom. Hence the sequence of first ionisation enthalpy in decreasing order is
`F gt N gt C`
But ionisation enthalpy of boron is less as compared to beryllium because first electron in boron is to be removed from p-orbital while in beryllium, is to be removed from s-orbital. More energy is required to remove electron from s-orbital as compared to p-orbital.
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