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Wht will be the theoretical value of mag...

Wht will be the theoretical value of magnetic moment `(mu)` when `CN^(-)` ligands join `Fe^(3+)` ion to yield complex

A

2.83 BM

B

3.87 BM

C

5.92 BM

D

1.73 BM

Text Solution

Verified by Experts

The correct Answer is:
D

Valence shell electronic configuration of

`CN^-` is a strong field ligand, so it forms low spin complexes after pairing of electrons within 3d level. Magnetic moment ` = sqrt(n(n+2)) B.M`
(where n = number of unpaired electrons)
` = sqrt(1(1+2)) BM = 1.73 BM`
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