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Replacement of Cl of chlorobenzene to gi...

Replacement of `Cl` of chlorobenzene to give phenol require drastic conditions but chlorine of `2,4`-dinitrochlorobenzene is readily replaced because .

A

`-NO_2` group makes the ring electron rich at ortho and para positions

B

`-NO_2` group withdraws electrons from meta position

C

`-NO_2` donates electrons at meta positions

D

`-NO_2` withdraws electrons from ortho and para positions

Text Solution

Verified by Experts

The correct Answer is:
D

`-NO_2`withdraws electrons from the carbon chloride group making the C - Cl bond weak.
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ERRORLESS-ALCOHOLS, PHENOLS AND ETHERS-NCERT BASED QUESTIONS (Different Ethers and Hydroxy Compounds)
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  2. Which of the following compounds on boiling with alkaline KMnO4 and s...

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  3. Which of the following species can act as the strongest base ?

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  4. Which of the following is most acidic ?

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  5. Acetyl chloride does not react with

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  6. If there be a compound of the formula CH(3)C(OH) which one of the foll...

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  7. Match the following Column A to Column B

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  8. The major product formed in the following reaction CH3CH(Cl)CH2-CH2O...

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  9. One mole of an organic compound A with the formula C(3)H(8)O reacts co...

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  10. Replacement of Cl of chlorobenzene to give phenol require drastic cond...

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  11. Predict the product C in the following series of reactions , CH3-COOH ...

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  12. From the following figure, the correct observation is :-

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  14. Which of the following compounds will react with sodium hydroxide solu...

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  15. Match the following Column A to Column B

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  16. In which of the following reaction, phenol or sodium phenoxide is not ...

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  17. In the reaction for dinitration The major dinitrated product X i...

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  18. Which of the following reactions is correctly represented?

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  19. Which of the following reacts fastest with conc. HCl ?

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  20. Match the following Column A to Column B

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