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The presence of the chlorine atom on ben...

The presence of the chlorine atom on benzene ring makes the second substituent enter at a position

A

Ortho

B

Meta

C

Para

D

Ortho-para

Text Solution

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The correct Answer is:
D
Chlorine atom is ortho-para directing group
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In the electrophilic substituion of benzene ring, the second substituent is directed by the group already present. Electron releasing groups (+I and +M) are ortho-para-directing and activating, whreas the electron withdrawing groups (-I and -M) are meta-directing and deactivating. Halogens are placed under the category of +T (Tautomeric) groups because they have -Ibdyctuve abd +Mesomeric effect. These groups are deactivating but ortho-para-directing. In the introduction of third group to the benzene ring, the product of minimum steric gindrance is formed. Which of the following substituted benzene derivatives would furmish three isomers when one more substituent is introduced ?

In the electrophilic substituion of benzene ring, the second substituent is directed by the group already present. Electron releasing groups (+I and +M) are ortho-para-directing and activating, whreas the electron withdrawing groups (-I and -M) are meta-directing and deactivating. Halogens are placed under the category of +T (Tautomeric) groups because they have -Ibdyctuve abd +Mesomeric effect. These groups are deactivating but ortho-para-directing. In the introduction of third group to the benzene ring, the product of minimum steric gindrance is formed. In the reaction Which of the following products is not formed at all ?

ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Dipole Moment, Resonance and Reaction Intermediates )
  1. The inequation that best describes the graph given below is <img ...

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  2. Which of the following is an electrophile ?

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  3. The presence of the chlorine atom on benzene ring makes the second sub...

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  4. Which kind of fission is favoured by sunlight

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  5. Which one of the following characteristics belongs to an electrophile?

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  6. The action of AlCl(3) in Frieded Craft's reaction is:

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  7. Strongest nucleophile is

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  8. CH(3)CH(2)Cl undergoes homolytic fission, produces

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  9. A nucleophile must have :

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  10. Carbocation which is most stable

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  11. Convalent bond can undergo fission in two different ways. The correct ...

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  12. Which one of the following will be the most easiliy attacked by an ele...

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  13. Reactivity towards nucleophilic additions reaction of (I) IHCHO (II), ...

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  14. Least active electrophile is :

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  15. The correct order of leaving group ability in a nucleophilic substitut...

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  16. Among the following compounds which can be dehydrated very easily is:

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  17. Which of the following compounds are not arranged in order of decreasi...

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  18. Which one of the following behaves both as a nucleophile and an electr...

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  19. Electrophilic additions reactions proceed in two steps. The first step...

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  20. The additions of HCl to an alkene proceeds in two steps. The first ste...

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