Home
Class 11
CHEMISTRY
Strongest nucleophile is...

Strongest nucleophile is

A

`RNH_(2)`

B

`ROH`

C

`C_(6) H_(5) O^(-)`

D

`CH_(3) O^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest nucleophile, we need to understand what a nucleophile is and the factors that influence nucleophilicity. ### Step-by-Step Solution: 1. **Definition of Nucleophile**: A nucleophile is a species that donates an electron pair to form a chemical bond in a reaction. Nucleophiles are typically negatively charged or neutral molecules with lone pairs of electrons. 2. **Factors Affecting Nucleophilicity**: Several factors influence the strength of a nucleophile: - **Charge**: Negatively charged species are generally stronger nucleophiles than their neutral counterparts. - **Electronegativity**: Less electronegative atoms are better nucleophiles because they hold onto their electrons less tightly. - **Solvent Effects**: In polar protic solvents, nucleophilicity decreases with increasing size due to solvation effects. In polar aprotic solvents, larger nucleophiles are stronger because they are less solvated. 3. **Comparison of Common Nucleophiles**: Common nucleophiles include: - \( \text{OH}^- \) (hydroxide) - \( \text{CH}_3\text{O}^- \) (methoxide) - \( \text{I}^- \) (iodide) - \( \text{Br}^- \) (bromide) - \( \text{Cl}^- \) (chloride) 4. **Identifying the Strongest Nucleophile**: Among the common nucleophiles, \( \text{CH}_3\text{O}^- \) (methoxide) is often cited as one of the strongest nucleophiles due to its negative charge and the presence of a lone pair of electrons on the oxygen atom. However, in some contexts, \( \text{Cs}_3\text{O}^- \) (cesium oxide) is mentioned as the strongest nucleophile because of the larger size of cesium, which makes the negative charge more available for donation. 5. **Conclusion**: Therefore, based on the information provided and the factors influencing nucleophilicity, \( \text{Cs}_3\text{O}^- \) is considered one of the strongest nucleophiles. ### Final Answer: The strongest nucleophile is \( \text{Cs}_3\text{O}^- \) (cesium oxide).

To determine the strongest nucleophile, we need to understand what a nucleophile is and the factors that influence nucleophilicity. ### Step-by-Step Solution: 1. **Definition of Nucleophile**: A nucleophile is a species that donates an electron pair to form a chemical bond in a reaction. Nucleophiles are typically negatively charged or neutral molecules with lone pairs of electrons. 2. **Factors Affecting Nucleophilicity**: ...
Promotional Banner

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY

    ERRORLESS|Exercise NCERT BASED QUESTIONS (Organic Reactions and their Mechanism )|46 Videos
  • GENERAL ORGANIC CHEMISTRY

    ERRORLESS|Exercise NCERT BASED QUESTIONS (Structural and Stereo Isomerism )|99 Videos
  • GENERAL ORGANIC CHEMISTRY

    ERRORLESS|Exercise ASSERTION AND REASON|14 Videos
  • ENVIRONMENTAL CHEMISTRY

    ERRORLESS|Exercise ASSERTION & REASON|7 Videos
  • HYDROCARBONS

    ERRORLESS|Exercise ASSERTION & REASON|18 Videos

Similar Questions

Explore conceptually related problems

Among the following the strongest nucleophilic is

Which of the following is the strongest nucleophile ?

Which of the following is the strongest nucleophile ?

A nucleophile is:

Which of the following is the strongest nucleophile?

ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Dipole Moment, Resonance and Reaction Intermediates )
  1. Which one of the following characteristics belongs to an electrophile?

    Text Solution

    |

  2. The action of AlCl(3) in Frieded Craft's reaction is:

    Text Solution

    |

  3. Strongest nucleophile is

    Text Solution

    |

  4. CH(3)CH(2)Cl undergoes homolytic fission, produces

    Text Solution

    |

  5. A nucleophile must have :

    Text Solution

    |

  6. Carbocation which is most stable

    Text Solution

    |

  7. Convalent bond can undergo fission in two different ways. The correct ...

    Text Solution

    |

  8. Which one of the following will be the most easiliy attacked by an ele...

    Text Solution

    |

  9. Reactivity towards nucleophilic additions reaction of (I) IHCHO (II), ...

    Text Solution

    |

  10. Least active electrophile is :

    Text Solution

    |

  11. The correct order of leaving group ability in a nucleophilic substitut...

    Text Solution

    |

  12. Among the following compounds which can be dehydrated very easily is:

    Text Solution

    |

  13. Which of the following compounds are not arranged in order of decreasi...

    Text Solution

    |

  14. Which one of the following behaves both as a nucleophile and an electr...

    Text Solution

    |

  15. Electrophilic additions reactions proceed in two steps. The first step...

    Text Solution

    |

  16. The additions of HCl to an alkene proceeds in two steps. The first ste...

    Text Solution

    |

  17. The correct order for homolytic bond dissociation energies (Delta H in...

    Text Solution

    |

  18. Among the following the strongest nucleophilic is

    Text Solution

    |

  19. For an electrophilic aromatic substitution reaction

    Text Solution

    |

  20. Which one of the following has the most nucleophilic nitrogen?

    Text Solution

    |