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CH(3)CH(2)Cl undergoes homolytic fission...

`CH_(3)CH_(2)Cl` undergoes homolytic fission, produces

A

`CH_(3) overset(**)( C) H_(2)` and `overset(**)( C)l`

B

`CH_(3) overset(oplus) (C )H_(2)` and `Cl^(Theta)`

C

`CH_(3) overset(oplus) (C )H_(2)` and `overset(**) (C )l`

D

`CH_(3) overset(**) ( C) H_(2)` and `Cl^(Theta)`

Text Solution

Verified by Experts

The correct Answer is:
B

`CH_(3) CH_(2) -Cl overset("heterolytic") underset("fission") (to) CH_(3) overset(oplus) ( C) H_(2) + Cl^(-)`
Due to polarity of C–Cl bond and high electronegativity of Cl with respect to carbon, Cl is detached with a pair of electrons.
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ERRORLESS-GENERAL ORGANIC CHEMISTRY -NCERT BASED QUESTIONS (Dipole Moment, Resonance and Reaction Intermediates )
  1. The action of AlCl(3) in Frieded Craft's reaction is:

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  2. Strongest nucleophile is

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  3. CH(3)CH(2)Cl undergoes homolytic fission, produces

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  4. A nucleophile must have :

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  5. Carbocation which is most stable

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  6. Convalent bond can undergo fission in two different ways. The correct ...

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  7. Which one of the following will be the most easiliy attacked by an ele...

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  8. Reactivity towards nucleophilic additions reaction of (I) IHCHO (II), ...

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  9. Least active electrophile is :

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  10. The correct order of leaving group ability in a nucleophilic substitut...

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  11. Among the following compounds which can be dehydrated very easily is:

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  12. Which of the following compounds are not arranged in order of decreasi...

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  13. Which one of the following behaves both as a nucleophile and an electr...

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  14. Electrophilic additions reactions proceed in two steps. The first step...

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  15. The additions of HCl to an alkene proceeds in two steps. The first ste...

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  16. The correct order for homolytic bond dissociation energies (Delta H in...

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  17. Among the following the strongest nucleophilic is

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  18. For an electrophilic aromatic substitution reaction

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  19. Which one of the following has the most nucleophilic nitrogen?

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  20. The reaction of methyl trichloroacetate (Cl(3)"CC"O(2)Me) with sodium ...

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