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Statement I : Leachig of golds with cyan...

Statement I : Leachig of golds with cyanide ion in absence of air / `O_2` leads to cyano complex of Au(III).
Statement II: Zinc is oxidized during the displacement reaction carried out for gold extraction.
In the light of the above statements, choose the correct answer from the options given below.

A

Both statement I and statement II are correct.

B

Both statement I and statement II is incorrect.

C

Statement I is correct but statement II is incorrect

D

Statement I is incorrect but statement II is correct.

Text Solution

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The correct Answer is:
To solve the question, we need to analyze both statements provided: **Statement I:** Leaching of gold with cyanide ion in the absence of air/O₂ leads to the cyano complex of Au(III). **Statement II:** Zinc is oxidized during the displacement reaction carried out for gold extraction. ### Step-by-Step Solution: 1. **Understanding Leaching of Gold:** - Leaching is a process where gold is extracted from its ore using cyanide ions. The general reaction for gold leaching in the presence of oxygen is: \[ 4 \text{Au} + 8 \text{NaCN} + 2 \text{H}_2\text{O} \rightarrow 4 \text{Na[Au(CN)}_2] + 4 \text{NaOH} \] - In this reaction, gold (Au) is oxidized to Au(I) or Au(III) depending on the conditions. 2. **Analyzing the Absence of Air/O₂:** - In the absence of air or oxygen, the oxidation state of gold is not necessarily +3. Instead, it can remain in a lower oxidation state (like +1). Thus, the formation of a cyano complex of Au(III) is incorrect when there is no oxygen present. - Therefore, **Statement I is false**. 3. **Understanding the Role of Zinc in Gold Extraction:** - In the extraction process, after the gold is leached and forms a complex with cyanide, zinc is added to reduce the gold back to its metallic form: \[ \text{Na[Au(CN)}_2] + \text{Zn} \rightarrow \text{Au} + \text{Zn(CN)}_2 + \text{Na} \] - In this reaction, zinc (Zn) is oxidized from an oxidation state of 0 to +2, while gold is reduced from Au(I) or Au(III) back to Au(0). - Therefore, **Statement II is true**. 4. **Conclusion:** - Since Statement I is false and Statement II is true, the correct answer is that Statement I is incorrect, and Statement II is correct. ### Final Answer: - **Statement I is false; Statement II is true.**

To solve the question, we need to analyze both statements provided: **Statement I:** Leaching of gold with cyanide ion in the absence of air/O₂ leads to the cyano complex of Au(III). **Statement II:** Zinc is oxidized during the displacement reaction carried out for gold extraction. ### Step-by-Step Solution: ...
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