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Compound A reacts with NH4Cl and forms a...

Compound A reacts with `NH_4Cl` and forms a compound B. Compound B reacts with `H_2O `and excess of `CO_2` to form compound C which on passing through or reaction with saturated `NaCl` solution formssodium hydrogen carbonate. Compound A, B and C, are respectively

A

` CaCl_2, NH_4^+,(NH_4)_2CO_3`

B

`CaCl_2, NH_3, NH_4HCO_3`

C

`Ca(OH)_2, NH_3, NH_4HCO_3`

D

` Ca(OH)_2,NH_4^+,(NH4)_2CO3`

Text Solution

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The correct Answer is:
To solve the question step by step, we need to identify the compounds A, B, and C based on the reactions described. ### Step 1: Identify Compound A The question states that Compound A reacts with `NH4Cl`. A common reaction involving `NH4Cl` is with calcium hydroxide, which is `Ca(OH)2`. When calcium hydroxide reacts with ammonium chloride, it produces ammonia gas (`NH3`), calcium chloride (`CaCl2`), and water (`H2O`). **Reaction:** \[ \text{Ca(OH)}_2 + 2 \text{NH}_4\text{Cl} \rightarrow 2 \text{NH}_3 + \text{CaCl}_2 + 2 \text{H}_2\text{O} \] Thus, Compound A is **Calcium hydroxide (Ca(OH)2)**. ### Step 2: Identify Compound B From the reaction above, we can see that the product formed is ammonia (`NH3`). This ammonia can be considered as Compound B. ### Step 3: Identify Compound C Next, Compound B (ammonia) reacts with water and excess carbon dioxide to form ammonium bicarbonate (`NH4HCO3`). **Reaction:** \[ \text{NH}_3 + \text{H}_2\text{O} + \text{CO}_2 \rightarrow \text{NH}_4\text{HCO}_3 \] Thus, Compound C is **Ammonium bicarbonate (NH4HCO3)**. ### Step 4: Final Reaction with Sodium Chloride Finally, the question states that Compound C reacts with saturated sodium chloride solution to form sodium hydrogen carbonate (`NaHCO3`). The reaction can be represented as: **Reaction:** \[ \text{NH}_4\text{HCO}_3 + \text{NaCl} \rightarrow \text{NaHCO}_3 + \text{NH}_4\text{Cl} \] ### Conclusion Based on the above steps, we can summarize: - Compound A: **Calcium hydroxide (Ca(OH)2)** - Compound B: **Ammonia (NH3)** - Compound C: **Ammonium bicarbonate (NH4HCO3)** ### Final Answer Thus, the compounds A, B, and C are respectively: - **Calcium hydroxide (Ca(OH)2), Ammonia (NH3), Ammonium bicarbonate (NH4HCO3)**. ---
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