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Bond dissociation energy of E-H^(*) bond...

Bond dissociation energy of `E-H^(*)` bond of the order. A. ` O` B. `S` C. `Se` D. `Te` Choose the correct from the options given below:

A

`D gt C gt B gt A`

B

`B gt A gt C gt D`

C

`A gt B gt D gt C`

D

`A gt B gt C gt D`

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The correct Answer is:
To determine the bond dissociation energy of the `E-H` bond in the hydrides of group 16 elements (O, S, Se, Te), we can analyze the trend in bond dissociation energies based on the size of the atoms involved. ### Step-by-Step Solution: 1. **Identify the Hydrides**: The hydrides of group 16 elements we are considering are: - H₂O (water) - H₂S (hydrogen sulfide) - H₂Se (hydrogen selenide) - H₂Te (hydrogen telluride) 2. **Understand the Trend in Atomic Size**: As we move down the group from oxygen to tellurium, the atomic size increases due to the addition of electron shells. This means that: - Oxygen (O) is the smallest, - Sulfur (S) is larger than oxygen, - Selenium (Se) is larger than sulfur, - Tellurium (Te) is the largest. 3. **Relate Atomic Size to Bond Length and Strength**: The bond length increases as the size of the atom increases. A longer bond length generally leads to a weaker bond because the atoms are held together less tightly. Therefore, we can expect: - H-O bond (in H₂O) to be the strongest, - H-S bond (in H₂S) to be weaker than H-O bond, - H-Se bond (in H₂Se) to be weaker than H-S bond, - H-Te bond (in H₂Te) to be the weakest. 4. **Order of Bond Dissociation Energies**: Based on the above reasoning, we can conclude the order of bond dissociation energies for the `E-H` bonds is: - H₂O > H₂S > H₂Se > H₂Te 5. **Final Answer**: Therefore, the correct order of bond dissociation energy for the `E-H` bond is: - A (O) > B (S) > C (Se) > D (Te) ### Conclusion: The correct option is **A > B > C > D**, which corresponds to the order of bond dissociation energies of the `E-H` bonds in the hydrides of oxygen, sulfur, selenium, and tellurium.
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