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Answer any three of the following questi...

Answer any three of the following question :
(a) Explain the type of hybridization in `[Fe(CN)_6]^(3-)` on the basis of valence bond theory. (Given :Atomic number of Fe =26)
(b) Draw the geometrical isomers of `[PtCl_2(en)_2]^(2+)` ion.
(c) `[NiCl_4]^(2-)` is paramagnetic while `[Ni(CO)_4]` is diamagnetic through both are tetrahedral.Why?
(d) name the type of isomerism when ambidentate ligands are attached to central metal ion. Given one example of ambidentate ligand.

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(i) Write the geometrical isomer of the complex [Co(en)_(2)Cl_(2)]^(+) . (ii) [NiCl_(4)]^(2-) is paramagnetic while [Ni(CN)_(4)]^(2-) is diamagnetic through both are tetrahedral . Why ?

(a) What type of isomerism is shown by the complex [Co(NH_(3))_(5)(SCN)]^(2+) ? (b) why is [NiCl_(4)]^(2-) paramagnetic while [Ni(CN)_(4)]^(2-) is diamagnetic ? (Atomic number of Ni=28) (c) Why are low spin tetrahedral complexes rarely observed?

(a) For the complex [Fe(CN)_(6)]^(3-) , write the hybridisation type, magnetic character and spin nature of the complex .(At. Number : Fe = 26) (b) Draw one of the geometrical isomers of the complex [Pt(en)_(2)Cl_(2)]^(2+) which is optically active .

Explain on the basis of valence bond theory that [Ni(CN)_(4)]^(2-) ion iwth square planar structure is diamagnetic and [NiCl_(4)]^(2-) ion iwth tetrahedral geometry is paramagnetic.

Describe for any two of the following complex ions , the type of hybridisation , shape and magnetic property. (i) [Fe(H_(2)O)_6]^(2+) (ii) [Co(NH_3)_6]^(3+) (iii) [NiCl_4]^(2-)

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