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In a S(N^(2)) substitution reaction of t...

In a `S_(N^(2))` substitution reaction of the type
`R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)`
Which one of the following has the highest relative rate?

A

`{:(" "CH_(3)),(" |"),(CH_(3)-C-CH_(2)Br),(" |"),(" "CH_(3)):}`

B

`CH_(3)CH_(2)Br`

C

`CH_(3)-CH_(2)-CH_(2)Br`

D

`CH_(3)-underset(CH_(3))underset("| ")(CH)-CH_(2)Br`

Text Solution

Verified by Experts

The correct Answer is:
B

As primary is more reactive than secondary and tertiary alkyl halides so `CH_(3)CH_(2)Br` has the highest relative rate.
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