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An organic compound (C3H9N) (A) when tre...

An organic compound `(C_3H_9N)` `(A)` when treated with nitrous acid , gave an alcohol and `N_2` gas was evolved. (A) on warming with `CHCl_3` and caustiv potash gave `(C)` which on reduction gave isopropylmethylamine. Predict the structure of (A).

A

`CH_(3)CH_(2)-NH_CH_(3)`

B

`CH_(3)-underset(CH_(3))underset("| ")"N"-CH_(3)`

C

`CH_(3)CH_(2)CH_(2)-NH_(2)`

D

Text Solution

Verified by Experts

The correct Answer is:
D

`underset((A))(CH_(3)-underset(CH_(3))underset("| ")"CH"-NH_(2))overset(CHCl_(3))underset(KOH)rarrunderset((C))(CH_(3)-underset(CH_(3))underset("| ")"CH"-N)overset(rarr)=overset("Reduction")rarrCH_(3)-underset(CH_(3))underset("| ")"CH"-NH-CH_(3)`
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